tricyclo[3.3.1.1~3,7~]tetraphosphoxane 1,3,5-trioxide

Base Information

• Chemical Name: tricyclo[3.3.1.1~3,7~]tetraphosphoxane 1,3,5-trioxide
• CAS No.: 12037-11-5
• Molecular Formula: O9P4
• Molecular Weight: 267.89
• DSSTox Substance ID: DTXSID70152823
• Wikidata: Q83019578
• Mol file: 12037-11-5.mol

Synonyms:Phosphorusoxide (P4O9) (7CI,8CI); Tetraphosphorus nonaoxide

Chemical Property of tricyclo[3.3.1.1~3,7~]tetraphosphoxane 1,3,5-trioxide

Chemical Property:

• XLogP3: -1.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 9
• Rotatable Bond Count: 0
• Exact Mass: 267.84927956
• Heavy Atom Count: 13
• Complexity: 320

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: O=P12OP3OP(=O)(O1)OP(=O)(O3)O2

Technology Process of tricyclo[3.3.1.1~3,7~]tetraphosphoxane 1,3,5-trioxide

There total 2 articles about tricyclo[3.3.1.1~3,7~]tetraphosphoxane 1,3,5-trioxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

phosphorus(III) oxide (12440-00-5) → tetraphosphorus octaoxide (70983-17-4) + P4O7 (12065-80-4) + tetraphosphorus nonaoxide (12037-11-5) + phosphorus pentoxide (16752-60-6)

Guidance literature:

With oxygen; In solid matrix; Irradiation (UV/VIS); codeposition of microwave-discharged Ar/O2 mixt. (50/1-100/1) with Ar/P4O6 (15+/-2 K), photolysis (filtered mercury arc);

DOI:10.1021/j100345a024

Reference yield:

phosphorus(III) oxide (12440-00-5) → tetraphosphorus nonaoxide (12037-11-5)

Guidance literature:

In neat (no solvent); byproducts: P4O7, P4O8; heating P4O6 in a sealed glass tube under dry Ar at 723K;; extn. of P4O7 and P4O8 with 1,4-dioxane;;

Reference yield:

tetraphosphorus nonaoxide (12037-11-5) → trimetaphosphoric acid (13566-25-1) + phosphorous acid trimethyl ester (121-45-9)

Guidance literature:

With methanol; In benzene; molar ratio : P4O9:CH3OH=1:3;

upstream raw materials:

phosphorus(III) oxide

Downstream raw materials:

trimetaphosphoric acid

phosphorous acid trimethyl ester

Refernces