C₃₂H₄₆O₆Si

Base Information

• Chemical Name: C₃₂H₄₆O₆Si
• CAS No.: 1352816-02-4
• Molecular Formula: C₃₂H₄₆O₆Si
• Molecular Weight: 554.799
• Mol file: 1352816-02-4.mol

Synonyms:C₃₂H₄₆O₆Si

Chemical Property of C₃₂H₄₆O₆Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₂H₄₆O₆Si

There total 7 articles about C₃₂H₄₆O₆Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

C36H48O7Si (1352816-01-3) → C32H46O6Si (1352816-02-4)

Guidance literature:

C₃₆H₄₈O₇Si; With dimethylsulfide borane complex; In tetrahydrofuran; at 20 ℃; for 24h;

In water; at 20 ℃; Cooling;

With diisobutylaluminium hydride; In tetrahydrofuran; at -25 ℃; for 95h; diastereoselective reaction;

DOI:10.1002/anie.201104681

Reference yield:

C14H18O6 → C32H46O6Si (1352816-02-4)

Guidance literature:

Multi-step reaction with 6 steps

1.1: potassium hexamethylsilazane / tetrahydrofuran / 1 h / -78 °C

1.2: 1.08 h / -78 - 20 °C

2.1: titanium(IV) tetraethanolate / ethanol / Heating

3.1: toluene-4-sulfonic acid / benzene / 17 h / Reflux

4.1: potassium hexamethylsilazane / tetrahydrofuran / -45 - -40 °C

4.2: 0.75 h / -40 - -30 °C

5.1: 9-bora-bicyclo[3.3.1]nonane / tetrahydrofuran / 2 h / 20 °C

5.2: 14.2 h / 45 °C

6.1: dimethylsulfide borane complex / tetrahydrofuran / 24 h / 20 °C

6.2: NaBO₃*4H₂O / 20 °C / Cooling

6.3: 95 h / -25 °C

With titanium(IV) tetraethanolate; dimethylsulfide borane complex; potassium hexamethylsilazane; toluene-4-sulfonic acid; 9-bora-bicyclo[3.3.1]nonane; In tetrahydrofuran; ethanol; benzene; 5.2: Suzuki cross-coupling / 6.1: Hydroboration reaction;

DOI:10.1002/anie.201104681

Reference yield:

C20H28O7 (1352816-30-8) → C32H46O6Si (1352816-02-4)

Guidance literature:

Multi-step reaction with 5 steps

1.1: titanium(IV) tetraethanolate / ethanol / Heating

2.1: toluene-4-sulfonic acid / benzene / 17 h / Reflux

3.1: potassium hexamethylsilazane / tetrahydrofuran / -45 - -40 °C

3.2: 0.75 h / -40 - -30 °C

4.1: 9-bora-bicyclo[3.3.1]nonane / tetrahydrofuran / 2 h / 20 °C

4.2: 14.2 h / 45 °C

5.1: dimethylsulfide borane complex / tetrahydrofuran / 24 h / 20 °C

5.2: NaBO₃*4H₂O / 20 °C / Cooling

5.3: 95 h / -25 °C

With titanium(IV) tetraethanolate; dimethylsulfide borane complex; potassium hexamethylsilazane; toluene-4-sulfonic acid; 9-bora-bicyclo[3.3.1]nonane; In tetrahydrofuran; ethanol; benzene; 4.2: Suzuki cross-coupling / 5.1: Hydroboration reaction;

DOI:10.1002/anie.201104681

upstream raw materials:

C₂₀H₂₈O₇

C₁₇H₂₄O₇

C₁₈H₂₃F₃O₉S

3-(tert-butyldiphenylsilyloxy)prop-1-ene

Downstream raw materials:

C₃₂H₄₄O₅Si

Refernces