1-(4-Carboxyphenyl)-3,3-dimethyltriazene

Base Information

• Chemical Name: 1-(4-Carboxyphenyl)-3,3-dimethyltriazene
• CAS No.: 7203-91-0
• Deprecated CAS: 95536-27-9
• Molecular Formula: C9H11 N3 O2
• Molecular Weight: 193.205
• NSC Number: 228635,226089
• UNII: B1CBA7H4FG
• DSSTox Substance ID: DTXSID70866135
• Nikkaji Number: J55.465K
• ChEMBL ID: CHEMBL422037,CHEMBL4785461
• Mol file: 7203-91-0.mol

Synonyms:1-(4-carboxyphenyl)-3,3-dimethyltriazene;1-(4-carboxyphenyl)-3,3-dimethyltriazene, potassium salt;1-(4-carboxyphenyl)-3,3-dimethyltriazene, sodium salt;1-4-(3,3-dimethyl-1-triazeno)benzoic acid;1-4-carboxy-3,3-dimethylphenyltriazene;1-p-(3,3-dimethyl-1-triazeno)benzoic acid;CB 10-277;CB 10277;CB-10277;DM-COOK;DMTZB;para-(3,3-dimethyl-1-triazenyl)benzoic acid;potassium 4-(3,3-dimethyl-1-triazeno)benzoate

Chemical Property of 1-(4-Carboxyphenyl)-3,3-dimethyltriazene

Chemical Property:

• Vapor Pressure: 7.9E-05mmHg at 25°C
• Boiling Point: 328°C at 760 mmHg
• Flash Point: 152.1°C
• PSA: 65.26000
• Density: 1.19g/cm³
• LogP: 1.94510
• XLogP3: 1.9
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 3
• Exact Mass: 193.085126602
• Heavy Atom Count: 14
• Complexity: 220

Purity/Quality:

98% ^*data from raw suppliers

4-(DIMETHYLAMINODIAZENYL)BENZOIC ACID 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CN(C)N=NC1=CC=C(C=C1)C(=O)O

Technology Process of 1-(4-Carboxyphenyl)-3,3-dimethyltriazene

There total 5 articles about 1-(4-Carboxyphenyl)-3,3-dimethyltriazene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-amino-benzoic acid (150-13-0,159246-81-8,8014-65-1) → 3,3-dimethyl-1-(4-carboxyphenyl)-triazene (7203-91-0)

Guidance literature:

Multi-step reaction with 2 steps

1: NO₂ / 6 h / Ambient temperature

2: Ambient temperature

With Nitrogen dioxide;

DOI:10.1002/prac.19973390145

Reference yield:

p-carboxybenzene diazonium nitrate + dimethyl amine (124-40-3) → 3,3-dimethyl-1-(4-carboxyphenyl)-triazene (7203-91-0)

Guidance literature:

Yield given; gas-solid reaction;

Reference yield:

4-amino-benzoic acid (150-13-0,159246-81-8,8014-65-1) → 3,3-dimethyl-1-(4-carboxyphenyl)-triazene (7203-91-0)

Guidance literature:

Multi-step reaction with 2 steps

1: NO₂ / gas-solid reaction

2: gas-solid reaction

With Nitrogen dioxide;

upstream raw materials:

4-amino-benzoic acid

dimethyl amine

Downstream raw materials:

C₁₈H₂₀N₄O₃

C₁₁H₁₄N₄O₃

4-Carboxy-phenyl-diazonium

dimethyl amine

Refernces

• 1、 Kaupp, Gerd,Schmeyers, Jens,Haak, Michael,Marquardt, Thorsten,Herrmann, Andreas. "AFM in organic solid state reactions". . p. 315 - 317. Retrieved 2007/10/03.