Technology Process of 4,4'-bis[(p-allylphenyl)phenylamino]biphenyl
There total 3 articles about 4,4'-bis[(p-allylphenyl)phenylamino]biphenyl which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
N4,N4’-bis(4-bromophenyl)-N4,N4’-diphenyl-[1,1'-biphenyl]-4,4'-diamine;
With
n-butyllithium;
In
diethyl ether; hexane;
at 25 ℃;
for 2h;
allyl bromide;
With
copper(l) iodide;
In
diethyl ether; hexane;
at 0 - 20 ℃;
for 14h;
DOI:10.1021/ja051077w
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: 50 percent / tris(dibenzylideneacetone)dipalladium; bis(diphenylphosphino)ferrocene; sodium tert-butoxide / toluene / 12 h / 90 °C
2.1: n-BuLi / diethyl ether; hexane / 2 h / 25 °C
2.2: 70 percent / CuI / diethyl ether; hexane / 14 h / 0 - 20 °C
With
tris-(dibenzylideneacetone)dipalladium(0); n-butyllithium; 1,1'-bis(diphenylphosphino)ferrocene; sodium t-butanolate;
In
diethyl ether; hexane; toluene;
DOI:10.1021/ja051077w
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: 50 percent / tris(dibenzylideneacetone)dipalladium; bis(diphenylphosphino)ferrocene; sodium tert-butoxide / toluene / 12 h / 90 °C
2.1: n-BuLi / diethyl ether; hexane / 2 h / 25 °C
2.2: 70 percent / CuI / diethyl ether; hexane / 14 h / 0 - 20 °C
With
tris-(dibenzylideneacetone)dipalladium(0); n-butyllithium; 1,1'-bis(diphenylphosphino)ferrocene; sodium t-butanolate;
In
diethyl ether; hexane; toluene;
DOI:10.1021/ja051077w