B₁₀Cl₁₀

Base Information

• Chemical Name: B₁₀Cl₁₀
• CAS No.: 61674-49-5
• Molecular Formula: B₁₀Cl₁₀
• Molecular Weight: 462.64
• Mol file: 61674-49-5.mol

Synonyms:B₁₀Cl₁₀

Chemical Property of B₁₀Cl₁₀

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of B₁₀Cl₁₀

There total 4 articles about B₁₀Cl₁₀ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

trichlorofluoromethane (75-69-4) + diboron tetrachloride (13701-67-2) → nonachlorononaborane(9) (12008-47-8) + B10Cl10 (61674-49-5) + B8Cl8 (32915-80-3) + diboron tetrafluoride (13965-73-6)

Guidance literature:

In trichlorofluoromethane; byproducts: CCl4; B2Cl4 and 10-fold excess CCl3F were heated in a sealed tube at 90°C for 61 h; partially septd. by fractionation at -95 to -160°C; products detected by (19)F- and (11)B-NMR, CCl4 by (13)C-NMR;

Reference yield:

diboron tetrachloride (13701-67-2) → nonachlorononaborane(9) (12008-47-8) + B10Cl10 (61674-49-5) + boron trichloride (10294-34-5)

Guidance literature:

With tetrachloromethane; In gas; byproducts: HCl, Cl2, C6Cl6; vac. pyrolysis (340 and 420°C, varying molar ratio); fractional condensation, identification by MS and NMR;

DOI:10.1016/0022-328X(89)87014-7

Reference yield:

diboron tetrachloride (13701-67-2) → nonachlorononaborane(9) (12008-47-8) + B10Cl10 (61674-49-5) + B11Cl11 (12230-26-1) + (B9Cl8)2 + boron trichloride (10294-34-5)

Guidance literature:

In neat (no solvent); in a Pyrex tube, 0.5 h at 300°C; monitored by (11)B NMR and ESR;

upstream raw materials:

diboron tetrachloride

trichlorofluoromethane

Refernces

• 1、 Saulys,Castillo,Morrison. "Fluorination of boron chlorides and boron bromides by reaction with bis(trifluoromethyl)mercury, trichlorofluoromethane, or tribromofluoromethane: Synthesis of BF2B5H8". . p. 1619 - 1624. Retrieved 2008/10/08.