[(4-Nitrophenyl)sulfonyl] azide

Base Information

• Chemical Name: [(4-Nitrophenyl)sulfonyl] azide
• CAS No.: 4547-62-0
• Molecular Formula: C₆H₄N₄O₄S
• Molecular Weight: 228.188
• Mol file: 4547-62-0.mol

Synonyms:p-NO2-benzenesulfonyl azide;4-nosyl azide;Benzenesulfonyl azide,4-nitro;p-Nitrobenzenesulfonyl azide;p-Nitrophenylsulfonylazide;4-Nitrobenzenesulfonyl azide;p-NO2PhSO2N3;p-Nitrobenzenesulphonyl azide;4-NO2-PhSO2N3;Benzenesulfonyl azide,p-nitro;

Chemical Property of [(4-Nitrophenyl)sulfonyl] azide

Chemical Property:

• Melting Point: 100-101 °C
• PSA: 138.09000
• LogP: 2.65056

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of [(4-Nitrophenyl)sulfonyl] azide

There total 13 articles about [(4-Nitrophenyl)sulfonyl] azide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

4-Nitrobenzenesulfonyl chloride (98-74-8) → p-nitrobenzenesulfonyl azide (73901-01-6,4547-62-0)

Guidance literature:

With sodium azide; In water; acetone; at 0 - 20 ℃; for 11h; Sealed tube;

DOI:10.1021/acs.joc.9b01538

Reference yield: 92.0%

4-nitrobenzenesulfonyl fluoride (349-96-2) → p-nitrobenzenesulfonyl azide (73901-01-6,4547-62-0)

Guidance literature:

With trimethylsilylazide; 1,8-diazabicyclo[5.4.0]undec-7-ene; In acetonitrile; at 20 ℃; for 1h; Solvent; Reagent/catalyst;

DOI:10.1055/s-0035-1561626

Reference yield: 90.0%

4-nitrobenzenesulfonohydrazide (2937-05-5) → p-nitrobenzenesulfonyl azide (73901-01-6,4547-62-0)

Guidance literature:

With tert.-butylnitrite; In acetonitrile; at 27 - 29 ℃; for 0.25h;

DOI:10.1039/c8ob01950a

upstream raw materials:

4-Nitrobenzenesulfonyl chloride

4-nitrobenzenesulfonohydrazide

p-nitrobenzenesulfonic acid

p-nitrobenzenesulfonamide

Downstream raw materials:

N-Methyl-N-phenyl-N'-(4-nitrobenzolsulfonyl-formamidin

13-(4-Nitrobenzolsulfonimido)tetraspiro<2.0.2.0.2.0.2.1>tridecan

16-(4-Nitrobenzolsulfonimido)pentaspiro<2.0.2.0.2.0.2.0.2.1>hexadecan

3ξ-dimethylamino-2-(4-nitro-benzenesulfonyl)-(3br,5at)-3,3b,4,5,5a,6-hexahydro-2H-cyclobuta[4,5]cyclopenta[1,2-d]isoxazole

Refernces

• 1、 Jiang, Shuai,Cao, Wen-Bin,Li, Hai-Yan,Xu, Xiao-Ping,Ji, Shun-Jun. "Convenient synthesis of spiroindolenines from tryptamine-derived isocyanides and organic azides by cobalt catalysis in pure water". supporting information. p. 2619 - 2623. Retrieved 2021/04/21.
• 2、 Silaichev, Pavel S.,Beryozkina, Tetyana V.,Novikov, Mikhail S.,Dehaen, Wim,Bakulev, Vasiliy A.. "A Base-Controlled Reaction of 2-Cyanoacetamidines (3,3-Diaminoacrylonitriles) with Sulfonyl Azides as a Route to Nonaromatic 4-Methylene-1,2,3-triazole-5-imines". . p. 3688 - 3698. Retrieved 2020/06/09.