ethyl octyl carbonate

Base Information

• Chemical Name: ethyl octyl carbonate
• CAS No.: 45130-04-9
• Molecular Formula: C₁₁H₂₂O₃
• Molecular Weight: 202.294
• Mol file: 45130-04-9.mol

Synonyms:ethyl octyl carbonate

Chemical Property of ethyl octyl carbonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of ethyl octyl carbonate

There total 7 articles about ethyl octyl carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

octanol (111-87-5) + Diethyl carbonate (105-58-8,76619-83-5) → ethanol (64-17-5) + ethyl octyl carbonate (45130-04-9)

Guidance literature:

With phosphorus pentoxide; potassium carbonate; Aliquat 336; In neat (no solvent); for 24h; under 20 Torr; Ambient temperature;

DOI:10.1016/S0040-4039(00)80548-1

Reference yield: 71.0%

octylmagnesium bromide (17049-49-9) + chloroformic acid ethyl ester (541-41-3) → ethyl pelargonate (123-29-5) + ethyl octyl carbonate (45130-04-9)

Guidance literature:

With copper(I) bromide; lithium bromide; In tetrahydrofuran; at 20 ℃;

DOI:10.1055/s-2007-973861

Reference yield:

octanol (111-87-5) + Diethyl carbonate (105-58-8,76619-83-5) → diethyl ether (60-29-7,927820-24-4) + ethyl octyl ether (929-61-3) + ethanol (64-17-5) + di-n-octyl ether (629-82-3) + ethyl octyl carbonate (45130-04-9)

Guidance literature:

With aluminum oxide; at 150 ℃; for 8h; under 18751.9 Torr; Inert atmosphere;

DOI:10.1016/j.apcata.2011.10.037

upstream raw materials:

octanol

Diethyl carbonate

ethanol

octyl chloroformate

Downstream raw materials:

dioctyl carbonate

Refernces

• 1、 Guilera,Bringué,Ramírez,Iborra,Tejero. "Synthesis of ethyl octyl ether from diethyl carbonate and 1-octanol over solid catalysts. A screening study". body text. p. 21 - 29. Retrieved 2012/03/27.
• 2、 Bottalico, Daniela,Fiandanese, Vito,Marchese, Giuseppe,Punzi, Angela. "A new versatile synthesis of esters from Grignard reagents and chloroformates". . p. 974 - 976. Retrieved 2008/02/02.