(-)-(3-oxo-camphorsulphonyl)imine

Base Information

• Chemical Name: (-)-(3-oxo-camphorsulphonyl)imine
• CAS No.: 191212-13-2
• Molecular Formula: C₁₀H₁₃NO₃S
• Molecular Weight: 227.284
• Mol file: 191212-13-2.mol

Synonyms:(-)-(3-oxo-camphorsulphonyl)imine

Chemical Property of (-)-(3-oxo-camphorsulphonyl)imine

Chemical Property:

Purity/Quality:

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Technology Process of (-)-(3-oxo-camphorsulphonyl)imine

There total 1 articles about (-)-(3-oxo-camphorsulphonyl)imine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 26.6%

DL camphor-10-thiazine dioxide (104319-35-9) → 7,7-dimethyl-2,3-dioxo-bicyclo[2.2.1]heptane-4-methanesulfonic acid (367522-55-2,73413-79-3) + 7,7-dimethyl-2,3-dioxo-bicyclo[2.2.1]heptane-4-methanesulfonamide + Camphorquinone (2767-84-2,10334-26-6,10373-78-1,71074-96-9,105309-30-6,465-29-2) + (-)-(3-oxo-camphorsulphonyl)imine (191212-13-2)

Guidance literature:

With selenium(IV) oxide; In water; at 150 ℃; for 1.25h; Further byproducts given; microwave irradiation;

DOI:10.1080/00397910500501557

Reference yield: 85.0%

(-)-(3-oxo-camphorsulphonyl)imine (191212-13-2) → (3aS,7R)-8,8-dimethyl-7-hydroxy-1,1a,4,5,6,7-hexahydro-3H-3a,6-methano-2,1-benzisothiazole 2,2-dioxide (130748-66-2)

Guidance literature:

With aluminum isopropoxide; In isopropyl alcohol; for 720h; Heating;

Reference yield: 62.0%

N,N-diphenylhydrazine hydrochloride (530-47-2,29666-92-0) + (-)-(3-oxo-camphorsulphonyl)imine (191212-13-2) → (Z)-7-(2,2-diphenylhydrazono)-8,8-dimethyl-4,5,6,7-tetrahydro-3H-3a,6-methanobenzo[c]isothiazole 2,2-dioxide

Guidance literature:

N,N-diphenylhydrazine hydrochloride; With sodium acetate; In ethanol; at 20 ℃; for 1h; Inert atmosphere;

(-)-(3-oxo-camphorsulphonyl)imine; In ethanol; at 20 ℃; for 72h; Inert atmosphere;

DOI:10.1016/j.jinorgbio.2016.11.003

upstream raw materials:

DL camphor-10-thiazine dioxide

Downstream raw materials:

(3aS,7R)-8,8-dimethyl-7-hydroxy-1,1a,4,5,6,7-hexahydro-3H-3a,6-methano-2,1-benzisothiazole 2,2-dioxide

Refernces