diphenylantimony(III) acetate

Base Information

• Chemical Name: diphenylantimony(III) acetate
• CAS No.: 5613-52-5
• Molecular Formula: C₁₄H₁₃O₂Sb
• Molecular Weight: 335.006
• Mol file: 5613-52-5.mol

Synonyms:diphenylantimony(III) acetate

Chemical Property of diphenylantimony(III) acetate

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of diphenylantimony(III) acetate

There total 27 articles about diphenylantimony(III) acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

dichlorophenylstibine (5035-52-9) + sodium acetate trihydrate (6131-90-4) → antimony(III) acetate (6923-52-0) + diphenylantimony(III) acetate (5613-52-5)

Guidance literature:

In ethanol; byproducts: NaCl; refluxing, filtering, evapn., extrn. with benzene, evapn.;

Reference yield: 61.0%

antimony(III) chloride (10025-91-9) + triphenylantimony (603-36-1) → diphenylantimony(III) acetate (5613-52-5)

Guidance literature:

With sodium acetate; In methanol; Ph3Sb and SbCl3 were refluxed in CH2Cl2 for 3 d, solvent was removed and replaced by MeOH, Na acetate was added and mixt. refluxed for 12 h; solvent was removed, residue extd. with hot toluene, crystn. from toluene or glacial acetic acid; elem. anal.;

DOI:10.1016/S0022-328X(00)83484-1

Reference yield: 46.0%

benzenediazonium; tetrachloro antimonate (III) → phenylstibine oxide (4519-29-3) + diphenylantimony(III) acetate (5613-52-5) + triphenylantimony dichloride (594-31-0,34716-91-1,20265-29-6)

Guidance literature:

With Zn or Fe; In ethyl acetate; at 60°C;

upstream raw materials:

diphenylstibane

acetic acid

bis(diphenylantimony)oxide

(C₆H₅)2SbC₆H₄-2-CH₃

Downstream raw materials:

diphenylantimony(III) bromide

2-CH₃C₆H₄SSb(C₆H₅)2

bis(diphenylantimony)oxide

2,6-(CH₃)2C₆H₃SSb(C₆H₅)2

Refernces

• 1、 Silvestru, Christian,Curtui, Maria,Haiduc, Ionel,Begley, Michael J.,Sowerby, D. Bryan. "Phenylantimony(III) diorganophosphorodithioates: the crystal structure of diphenylantimony(III) di-isopropylphosphorodithioate, Ph2SbS2P(OiPr)2; unusual polymerisation through semibonding". . p. 49 - 58. Retrieved 2007/10/02.