(E)-1-Chloro-2,3,3,3-tetrafluoropropene

Base Information

• Chemical Name: (E)-1-Chloro-2,3,3,3-tetrafluoropropene
• CAS No.: 111512-52-8
• Molecular Formula: C₃HClF₄
• Molecular Weight: 148.488
• European Community (EC) Number: 824-262-8
• Nikkaji Number: J3.363.119G
• Mol file: 111512-52-8.mol

Synonyms:(E)-1-Chloro-2,3,3,3-tetrafluoropropene;(1E)-1-chloro-2,3,3,3-tetrafluoroprop-1-ene;111512-52-8;SCHEMBL70518;GDPWRLVSJWKGPJ-OWOJBTEDSA-N

Chemical Property of (E)-1-Chloro-2,3,3,3-tetrafluoropropene

Chemical Property:

• XLogP3: 2.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 147.9702904
• Heavy Atom Count: 8
• Complexity: 102

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C(=C(C(F)(F)F)F)Cl
• Isomeric SMILES: C(=C(\C(F)(F)F)/F)\Cl

Technology Process of (E)-1-Chloro-2,3,3,3-tetrafluoropropene

There total 5 articles about (E)-1-Chloro-2,3,3,3-tetrafluoropropene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,3-dichloro-1,1,1,2-tetrafluoropropane → E-1-chloro-2,3,3,3-tetrafluoro-1-propene (111512-52-8) + Z-1-chloro-2,3,3,3-tetrafluoro-1-propene (111512-60-8)

Guidance literature:

With tetrabutylammomium bromide; potassium hydroxide; In water; at 60 ℃; under 1500.15 Torr; Large scale;

Reference yield:

1,1-dichloro-2,3,3,3-tetrafluoro-1-propene (2804-55-9) → E-1-chloro-2,3,3,3-tetrafluoro-1-propene (111512-52-8) + Z-1-chloro-2,3,3,3-tetrafluoro-1-propene (111512-60-8)

Guidance literature:

1,1-dichloro-2,3,3,3-tetrafluoro-1-propene; With palladium on activated charcoal; hydrogen; at 80 ℃; for 0.00694444h;

With potassium hydroxide; In water; Molecular sieve;

Reference yield:

3-chloro-1,1,1,2,2-pentafluoropropane (422-02-6) → E-1-chloro-2,3,3,3-tetrafluoro-1-propene (111512-52-8) + Z-1-chloro-2,3,3,3-tetrafluoro-1-propene (111512-60-8)

Guidance literature:

chromium oxide activated with HF at 200-425C; at 350 ℃; for 0.00833333h; under 760.051 Torr;

upstream raw materials:

2,3,3-trichloro-1,1,1,2-tetrafluoropropane

3-chloro-1,1,1,2,2-pentafluoropropane

1-chloro-2,3,3,3-tetrafluoropropene

1,1-dichloro-2,3,3,3-tetrafluoro-1-propene

Refernces

• 1、 -. "METHOD OF PRODUCING HYDROCHLOROFLUOROOLEFIN AND METHOD OF PRODUCING 2,3,3,3-TETRAFLUOROPROPENE". Paragraph 0095; 0096; 0098; 0105; 0106. . Retrieved 2018/05/26.
• 2、 -. "PROCESSES FOR PRODUCING PENTAFLUOROPROPENES AND CERTAIN AZEOTROPES COMPRISING HF AND CERTAIN HALOPROPENES OF THE FORMULA C3HCIF4". Page/Page column 10. . Retrieved 2008/12/05.