Technology Process of C13H14Cl2NO9S2(1-)*K(1+)
There total 10 articles about C13H14Cl2NO9S2(1-)*K(1+) which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
potassium methanolate;
In
methanol;
at 20 ℃;
for 3h;
pH=8 - 9;
Inert atmosphere;
DOI:10.1016/j.bmc.2013.07.049
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: hydroxylamine hydrochloride; pyridine / methanol / 2.5 h / 20 °C
2.1: N-chloro-succinimide / N,N-dimethyl-formamide / 35 °C / Cooling with ice
3.1: triethylamine / dichloromethane; diethyl ether / 2 h / 20 °C / Inert atmosphere
4.1: sulfur trioxide pyridine complex / dichloromethane / 20 h / Reflux; Inert atmosphere
4.2: 0.5 h
5.1: potassium methanolate / methanol / 3 h / 20 °C / pH 8 - 9 / Inert atmosphere
With
pyridine; N-chloro-succinimide; hydroxylamine hydrochloride; potassium methanolate; sulfur trioxide pyridine complex; triethylamine;
In
methanol; diethyl ether; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/j.bmc.2013.07.049
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: N-chloro-succinimide / N,N-dimethyl-formamide / 35 °C / Cooling with ice
2.1: triethylamine / dichloromethane; diethyl ether / 2 h / 20 °C / Inert atmosphere
3.1: sulfur trioxide pyridine complex / dichloromethane / 20 h / Reflux; Inert atmosphere
3.2: 0.5 h
4.1: potassium methanolate / methanol / 3 h / 20 °C / pH 8 - 9 / Inert atmosphere
With
N-chloro-succinimide; potassium methanolate; sulfur trioxide pyridine complex; triethylamine;
In
methanol; diethyl ether; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/j.bmc.2013.07.049