1,1'-Azobis(cyclohexanecarbonitrile)

Base Information

• Chemical Name: 1,1'-Azobis(cyclohexanecarbonitrile)
• CAS No.: 2094-98-6
• Deprecated CAS: 95210-42-7
• Molecular Formula: C14H20N4
• Molecular Weight: 244.34
• Hs Code.: 2927000090
• European Community (EC) Number: 218-254-8
• UN Number: 1325
• UNII: 9Y0B93KKUS
• DSSTox Substance ID: DTXSID9044613
• Nikkaji Number: J36.141K
• Wikipedia: ABCN
• Wikidata: Q4650106
• ChEMBL ID: CHEMBL3183745
• Mol file: 2094-98-6.mol

Synonyms:2094-98-6;1,1'-Azobis(cyanocyclohexane);1,1'-Azobis(cyclohexanecarbonitrile);Cyclohexanecarbonitrile, azobis-;ABCN;ACHN;1-[(1-cyanocyclohexyl)diazenyl]cyclohexane-1-carbonitrile;1,1'-Azobiscyclohexanecarbonitrile;Azobis(cyclohexanecarbonitrile);25551-14-8;9Y0B93KKUS;1,1'-Azobis(1-cyclohexanecarbonitrile);VAZO-88;1,1'-Azobis cyanocyclohexane;DTXSID9044613;1,1'-azobis(1-cyanocyclohexane);1,1'-Diazene-1,2-diyldicyclohexanecarbonitrile;Cyclohexanecarbonitrile, 1,1'-azobis-;1,1'-azobis(cyclohexane-1-carbonitrile);1,1'-AZODI(HEXAHYDROBENZONITRILE);(E)-1,1'-(diazene-1,2-diyl)dicyclohexanecarbonitrile;1,1'-azobis[cyclohexane-1-carbonitrile];azobiscyclohexylnitrile;38811-43-7;UNII-9Y0B93KKUS;azobiscyclohexanecarbonitrile;azobis-(1-cyanocyclohexane);azobis(1-cyclohexanenitrile);azobiscyclohexane-carbonitrile;SCHEMBL21916;V-40 (INITIATOR);1,1-azobis(cyanocyclohexane);azobis(cyclohexane carbonitrile);SCHEMBL3792642;Azo-bis(cyclohexanecarbonitrile);1,1'-azobis(cyclohexylnitrile);CHEMBL3183745;DTXCID7024613;1,1'-azobis(cyclohexanenitrile);1-AZO-1-CYANOCYCLOHEXANE;AZOBIS(1-CYANOCYCLOHEXANE);EINECS 218-254-8;Tox21_303619;1,1'-azobis-cyclohexane carbonitrile;1,1'-azobis (cyclohexanecarbonitrile);1,1'-azobis(cyclo-hexanecarbonitrile);1,1'-azobis(cyclohexane carbonitrile);1,1'-azobis(cyclohexanecarbo-nitrile);AKOS015853608;AKOS025243290;AZOCYCLOHEXANE-1,1'-DINITRILE;GS-6043;1,1'-azobis (cyclohexane carbonitrile);1,1'-azobis(cyclo-hexane carbonitrile);1,1'-azobis-(cyclohexane carbonitrile);1,1'-azobis-(cyclohexane-carbonitrile);1,1'-azobis(cydohexane-1-carbonitrile);1,1'-AZODICYCLOHEXANECARBONITRILE;NCGC00256658-01;V-40;CAS-2094-98-6;N,N-AZOBIS(CYCLOHEXANECARBONITRILE);1,1'-Azobis(cyclohexanecarbonitrile), 98%;FT-0634035;CYCLOHEXANECARBONITRILE, 1,1'-AZODI-;H10521;1,1'-AZOBIS(CYCLOHEXANECARBONITRILE) [MI];1-(1-cyanocyclohexyl)azo-1-cyclohexanecarbonitrile;A815043;Q4650106;W-109749;[E]-1,1'[diazene-1,2-diyl)dicyclohexanecarbonitrile;Cyclohexanecarbonitrile, 1,1'-(1,2-diazenediyl)bis-;(E)-1,1'-(Diazene-1,2-diyl)bis(cyclohexane-1-carbonitrile);1-[(E)-2-(1-cyanocyclohexyl)diazen-1-yl]cyclohexane-1-carbonitrile;1-[(1E)-2-(1-cyanocyclohexyl)diazen-1-yl]cyclohexane-1-carbonitrile

Chemical Property of 1,1'-Azobis(cyclohexanecarbonitrile)

Chemical Property:

• Appearance/Colour: faintly beige crystalline powder
• Vapor Pressure: 0-0.001Pa at 20-25℃
• Melting Point: 114-118 °C(lit.)
• Boiling Point: 423.9ºC at 760 mmHg
• Flash Point: 210.2ºC
• PSA: 72.30000
• Density: 1.13 g/cm3
• LogP: 3.89156
• Storage Temp.: 2-8°C
• XLogP3: 3.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 2
• Exact Mass: 244.16879665
• Heavy Atom Count: 18
• Complexity: 368
• Transport DOT Label: Flammable Solid

Purity/Quality:

99% ^*data from raw suppliers

1,1′-Azobis(cyclohexanecarbonitrile) 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F, Xi
• Hazard Codes: F,Xi
• Statements: 11-36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CCC(CC1)(C#N)N=NC2(CCCCC2)C#N
• Uses: A more efficient radical initiator than AIBN has been employed to initiate primary radical reactions.

Technology Process of 1,1'-Azobis(cyclohexanecarbonitrile)

There total 6 articles about 1,1'-Azobis(cyclohexanecarbonitrile) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

1,2-di-1-(1-cyano)-cyclohexylhydrazine (17643-01-5) → 1,1'-azobis(1-cyanocyclohexanenitrile) (2094-98-6)

Guidance literature:

With trichloroisocyanuric acid; In acetonitrile; at 20 ℃;

Reference yield: 77.0%

1,2-di-1-(1-cyano)-cyclohexylhydrazine (17643-01-5) → 1,1'-azo-bis-cyclohexanecarbonitrile (2094-98-6)

Guidance literature:

With sodium cyanide; In methanol; electrolysis;

DOI:10.1021/jo00290a048

Reference yield:

1-(N-Dichloramino)cyclohexancarbonsaeurenitril (16248-80-9) → 1,1'-azobis(1-cyanocyclohexanenitrile) (2094-98-6)

Guidance literature:

With sodium hydroxide; In methanol;

upstream raw materials:

1-(N-Dichloramino)cyclohexancarbonsaeurenitril

1,2-di-1-(1-cyano)-cyclohexylhydrazine

Downstream raw materials:

1-benzyl-5-oxo-pyrrolidine-2-carboxylic acid methyl ester

2,3,5-tri-O-benzoyl-1-O-methyl-4-C-methyl-β-D-ribofuranose

N-(N-[(3,5-Dichlorobenzene)sulfonyl]octahydroisoindole-1(S)-carbonyl)-4-[(3',5'-dichloroisonicotinoyl-N-oxide)amino]-(L)-phenylalanine

2-(4-Bromomethyl-phenyl)-2-methyl-propionic acid ethyl ester

Refernces

• 1、 Wu et al.. "". . p. 5386,5392. Retrieved 1960.
• 2、 Mohite,Desai, Uday V.,Pore,Mane,Wadgaonkar. "Oxidation of 1,2-bis (cyanoalkyl) hydrazines to azobisnitriles using trichloroisocyanuric acid". . p. 645 - 646. Retrieved 2007/10/03.
• 3、 -. "Granules of azo-type compounds". . . Retrieved 2008/06/13.