2,7-Diiodophenanthrenequinone

Base Information

• Chemical Name: 2,7-Diiodophenanthrenequinone
• CAS No.: 16218-32-9
• Molecular Formula: C14H6I2O2
• Molecular Weight: 460.009
• Hs Code.: 2914700090
• Mol file: 16218-32-9.mol

Synonyms:Phenanthrenequinone,2,7-diiodo- (8CI);2,7-Diiodophenanthrenequinone;

Chemical Property of 2,7-Diiodophenanthrenequinone

Chemical Property:

• Melting Point: 309-310 °C
• Boiling Point: 547.1 °C at 760 mmHg
• Flash Point: 284.7 °C
• PSA: 34.14000
• Density: 2.263 g/cm³
• LogP: 3.94180
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature

Purity/Quality:

99% ^*data from raw suppliers

2,7-Diiodophenanthrene-9,10-dione 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,7-Diiodophenanthrenequinone

There total 4 articles about 2,7-Diiodophenanthrenequinone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

9,10-phenanthrenequinone (84-11-7) → 2,7-diiodophenanthrene-9,10-quinone (16218-32-9)

Guidance literature:

With N-iodo-succinimide; sulfuric acid; at 20 ℃; for 8h;

DOI:10.1021/acs.joc.1c01533

Reference yield: 32.0%

9,10-phenanthrenequinone (84-11-7) → 2-iodo-9,10-phenanthrenequinone (16218-31-8) + 2,7-diiodophenanthrene-9,10-quinone (16218-32-9)

Guidance literature:

With sulfuric acid; Iodine monochloride; at 90 - 95 ℃; for 10h;

Reference yield:

→ 2,7-diiodophenanthrene-9,10-quinone (16218-32-9)

Guidance literature:

With potassium iodide;

upstream raw materials:

9,10-phenanthrenequinone

Downstream raw materials:

2,7-Bis-phenylethynyl-phenanthrene-9,10-dione

10,10-bis(4-hydroxy-phenyl)-2,7-diiodo-10H-phenanthren-9-one

10,10-bis(4-hexyloxy-phenyl)-2,7-diiodo-10H-phenanthren-9-one

9,10-bis(4-hexyloxy-phenyl)-2,7-diiodo-phenanthrene

Refernces

• 1、 Butkute, Rita,Lygaitis, Ramunas,Mimaite, Viktorija,Gudeika, Dalius,Volyniuk, Dmytro,Sini, Gjergji,Grazulevicius, Juozas Vidas. "Bipolar highly solid-state luminescent phenanthroimidazole derivatives as materials for blue and white organic light emitting diodes exploiting either monomer, exciplex or electroplex emission". . p. 425 - 437. Retrieved 2017.
• 2、 -. "Rechargeable Aluminum Organic Batteries". Paragraph 0107; 0108. . Retrieved 2021/08/06.