[6,6'-diphenyl-[2,2']-bipyridinyl]NiBr₂

Base Information

• Chemical Name: [6,6'-diphenyl-[2,2']-bipyridinyl]NiBr₂
• CAS No.: 1403850-13-4
• Molecular Formula: C₂₂H₁₆Br₂N₂Ni
• Molecular Weight: 526.88
• Mol file: 1403850-13-4.mol

Synonyms:[6,6'-diphenyl-[2,2']-bipyridinyl]NiBr₂

Chemical Property of [6,6'-diphenyl-[2,2']-bipyridinyl]NiBr₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [6,6'-diphenyl-[2,2']-bipyridinyl]NiBr₂

There total 3 articles about [6,6'-diphenyl-[2,2']-bipyridinyl]NiBr₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.6%

nickel(II) bromide dimethoxyethane (28923-39-9) + 6,6’-diphenyl-2,2’-bipyridine (85575-95-7) → [6,6'-diphenyl-[2,2']-bipyridinyl]NiBr2 (1403850-13-4)

Guidance literature:

With acetic acid; for 4h; Inert atmosphere; Schlenk technique;

DOI:10.1016/j.jorganchem.2012.08.005

Reference yield:

2-phenylpyridine (1008-89-5) → [6,6'-diphenyl-[2,2']-bipyridinyl]NiBr2 (1403850-13-4)

Guidance literature:

Multi-step reaction with 2 steps

1.1: 2-(N,N-dimethylamino)ethanol / hexane / 0.5 h / Inert atmosphere; Schlenk technique

1.2: 0.5 h / 0 °C / Inert atmosphere; Schlenk technique

1.3: 1 h / -78 °C / Inert atmosphere; Schlenk technique

2.1: acetic acid / 4 h / Inert atmosphere; Schlenk technique

With 2-(N,N-dimethylamino)ethanol; acetic acid; In hexane;

DOI:10.1016/j.jorganchem.2012.08.005

Reference yield:

N,N-dimethylbenzamide (611-74-5) → [6,6'-diphenyl-[2,2']-bipyridinyl]NiBr2 (1403850-13-4)

Guidance literature:

Multi-step reaction with 2 steps

1.1: 2-(N,N-dimethylamino)ethanol / hexane / 0.5 h / Inert atmosphere; Schlenk technique

1.2: 0.5 h / 0 °C / Inert atmosphere; Schlenk technique

1.3: 1 h / -78 °C / Inert atmosphere; Schlenk technique

2.1: acetic acid / 4 h / Inert atmosphere; Schlenk technique

With 2-(N,N-dimethylamino)ethanol; acetic acid; In hexane;

DOI:10.1016/j.jorganchem.2012.08.005

upstream raw materials:

2-phenylpyridine

nickel(II) bromide dimethoxyethane

6,6’-diphenyl-2,2’-bipyridine

N,N-dimethylbenzamide

Refernces