Triethyl orthobutyrate

Base Information

• Chemical Name: Triethyl orthobutyrate
• CAS No.: 24964-76-9
• Molecular Formula: C10H22O3
• Molecular Weight: 190.283
• Hs Code.: 2909199090
• Mol file: 24964-76-9.mol

Synonyms:Orthobutyricacid, triethyl ester (8CI);1,1,1-Triethoxybutane;Ethyl orthobutyrate;NSC646223;Triethyl orthobutanoate;Triethyl orthobutyrate;

Chemical Property of Triethyl orthobutyrate

Chemical Property:

• Appearance/Colour: colorless Liquid
• Vapor Pressure: 0.496mmHg at 25°C
• Refractive Index: 1.417
• Boiling Point: 198.9 °C at 760 mmHg
• Flash Point: 67.7 °C
• PSA: 27.69000
• Density: 0.894 g/cm³
• LogP: 2.54980

Purity/Quality:

99% ^*data from raw suppliers

Triethyl Orthobutyrate ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Triethyl orthobutyrate

There total 5 articles about Triethyl orthobutyrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ethanol (64-17-5) + crotonaldehyde (123-73-9,4170-30-3) → triethyl orthobutyrate (24964-76-9)

Guidance literature:

With toluene-4-sulfonic acid; at 78 ℃; for 7h; Temperature; Time;

Reference yield:

ethanol (64-17-5) + ethyl butyrimidate hydrochloride (2208-08-4) → triethyl orthobutyrate (24964-76-9)

Guidance literature:

With diethyl ether;

Reference yield:

ethanol (64-17-5) + 1,1,1-trimethoxybutane (43083-12-1) → triethyl orthobutyrate (24964-76-9) + C8H18O3 + C9H20O3

Guidance literature:

With trifluoroacetic acid; In benzene-d6; at 20 ℃; for 1h;

DOI:10.1039/c4sc03528c

upstream raw materials:

ethanol

ethyl butyrimidate hydrochloride

N,N-diethyl-butyramide

1,1,1-trimethoxybutane

Downstream raw materials:

2-propyloxazolo<4,5-b>pyridine

9α-fluoro-11β,17α,21-trihydroxy-16β-methyl-1,4-pregnadiene-3,6,20-trione 17-butyrate

N-Phenylbutanimidsaeure-ethylester

2‐phenyl‐5‐propyl‐1,3,4‐oxadiazole

Refernces

• 1、 Brachvogel, Ren-Chris,Von Delius, Max. "Orthoester exchange: A tripodal tool for dynamic covalent and systems chemistry". . p. 1399 - 1403. Retrieved 2015/02/05.
• 2、 Tsakotellis,Johnson,Skinner,Skidmore,Maibach. "Topical mosquito repellents. 3. Carboxamide acetals and ketals and related carbonyl addition derivatives.". . p. 84 - 89. Retrieved 2007/10/09.