2-Bromoethyl benzoate

Base Information

• Chemical Name: 2-Bromoethyl benzoate
• CAS No.: 939-54-8
• Molecular Formula: C9H9BrO2
• Molecular Weight: 229.073
• Hs Code.: 29163100
• Mol file: 939-54-8.mol

Synonyms:Ethanol,2-bromo-, benzoate (6CI,7CI,8CI,9CI);2-Bromoethyl benzoate;b-Bromoethyl benzoate;

Chemical Property of 2-Bromoethyl benzoate

Chemical Property:

• Vapor Pressure: 0.000119mmHg at 25°C
• Refractive Index: n20/D 1.548(lit.)
• Boiling Point: 280.4 °C at 760 mmHg
• Flash Point: 123.4 °C
• PSA: 26.30000
• Density: 1.445 g/cm³
• LogP: 2.23830
• Storage Temp.: Refrigerator, under inert atmosphere
• Solubility.: Chloroform (Slightly), Methanol (Slightly)

Purity/Quality:

98%,99%, ^*data from raw suppliers

2-BromoethylBenzoate(~90%) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Useful:

• Uses: 2-Bromoethyl benzoate may be used in chemical synthesis.

Technology Process of 2-Bromoethyl benzoate

There total 23 articles about 2-Bromoethyl benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

C9H10O3 (94-33-7) → 2-bromoethyl benzoate (939-54-8)

Guidance literature:

With N-Bromosuccinimide; triphenylphosphine; In dichloromethane; at -78 - 20 ℃;

DOI:10.1021/ja042929f

Reference yield: 94.0%

benzaldehyde (100-52-7) + ethylene glycol (107-21-1) → 2-bromoethyl benzoate (939-54-8)

Guidance literature:

With pyridinium hydrobromide perbromide; orthoformic acid triethyl ester; In 1,2-dichloro-ethane; at 50 ℃; for 2h;

DOI:10.1016/j.tetlet.2005.01.159

Reference yield: 92.0%

2-phenyl-1,3-dioxolane (936-51-6) → 2-bromoethyl benzoate (939-54-8)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); Bromoform; In benzene; for 5h; Heating;

DOI:10.1080/00397919708005032

upstream raw materials:

oxirane

Benzoyl bromide

tetrachloromethane

N-Bromosuccinimide

Downstream raw materials:

3',5'-O-bis-tetrahydropyranyl-N₃-(2-benzoyl-ethyl)thymidine

benzoic acid

1,1,2,2-tetraphenylethylene

benzoic acid ethyl ester

Refernces

• 1、 Talukdar, Ranadeep. "IrIII-Catalyzed direct syntheses of amides and esters using nitriles as acid equivalents: A photochemical pathway". supporting information. p. 5303 - 5308. Retrieved 2020/04/17.
• 2、 Sriramoju, Vinodkumar,Jillella, Raveendra,Kurva, Srinivas,Madabhushi, Sridhar. "A study on reactions of an alkynylsilane with oxone-KX (X = Cl, Br, I) and its one-pot transformation into an amide/ester". supporting information. p. 560 - 562. Retrieved 2017/03/30.