1-bromo-4-t-butyl-2,6-diisopropylbenzene

Base Information

• Chemical Name: 1-bromo-4-t-butyl-2,6-diisopropylbenzene
• CAS No.: 1042326-18-0
• Molecular Formula: C₁₆H₂₅Br
• Molecular Weight: 297.279
• Mol file: 1042326-18-0.mol

Synonyms:1-bromo-4-t-butyl-2,6-diisopropylbenzene

Chemical Property of 1-bromo-4-t-butyl-2,6-diisopropylbenzene

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 1-bromo-4-t-butyl-2,6-diisopropylbenzene

There total 1 articles about 1-bromo-4-t-butyl-2,6-diisopropylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-tert-butyl-3,5-diisopropylbenzene (89784-61-2) → 1-bromo-4-t-butyl-2,6-diisopropylbenzene (1042326-18-0)

Guidance literature:

With bromine; iron; In tetrachloromethane; at 0 ℃; for 4h; Inert atmosphere;

DOI:10.1021/ja8041542

Reference yield: 89.0%

1-bromo-4-t-butyl-2,6-diisopropylbenzene (1042326-18-0) + 4-pyridylboronic acid (1692-15-5) → C21H29N

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; caesium carbonate; In 1,4-dioxane; water; at 90 ℃; for 5h; Inert atmosphere;

Reference yield:

1-bromo-4-t-butyl-2,6-diisopropylbenzene (1042326-18-0) + (S)-3,3’-diiodo-2,2’-dimethoxy-1,1’-binaphthyl → C54H66O2

Guidance literature:

1-bromo-4-t-butyl-2,6-diisopropylbenzene; With magnesium; ethylene dibromide; In diethyl ether; for 12.5h; Reflux; Inert atmosphere;

(S)-3,3’-diiodo-2,2’-dimethoxy-1,1’-binaphthyl; With bis(triphenylphosphine)nickel(II) chloride; In diethyl ether; at 20 ℃; for 24h; Reflux; Inert atmosphere;

DOI:10.1021/ja8041542

upstream raw materials:

1-tert-butyl-3,5-diisopropylbenzene

Refernces