Cu(OC₆H₅)(P(C₆H₅)3)3

Base Information

• Chemical Name: Cu(OC₆H₅)(P(C₆H₅)3)3
• CAS No.: 36820-10-7
• Molecular Formula: C₆₀H₅₀CuOP₃
• Molecular Weight: 943.524
• Mol file: 36820-10-7.mol

Synonyms:Cu(OC₆H₅)(P(C₆H₅)3)3

Chemical Property of Cu(OC₆H₅)(P(C₆H₅)3)3

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Cu(OC₆H₅)(P(C₆H₅)3)3

There total 2 articles about Cu(OC₆H₅)(P(C₆H₅)3)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

Cu(CH3)(P(C6H5)3)2*0.5((C2H5)2O) → Cu(OC6H5)(P(C6H5)3)3 (36820-10-7)

Guidance literature:

With triphenylphosphine; phenol; In diethyl ether; inert atmosphere; -10°C; stirring; 7 h;; washed with Et2O; recrystd. from toluene; elem. anal.;;

DOI:10.1016/0022-328X(94)80138-X

Reference yield: 43.0%

tris(triphenylphosphino)copper(I) chloride (15709-76-9) + sodium phenoxide (139-02-6) → Cu(OC6H5)(P(C6H5)3)3 (36820-10-7)

Guidance literature:

In toluene; inert atmosphere; room temp.; stirring; 5 h;; filtered through Celite; concd.; ppt. washed with Et2O; dried in vacuo; elem. anal.;;

DOI:10.1016/0022-328X(94)80138-X

Reference yield: 45.0%

Cu(OC6H5)(P(C6H5)3)3 (36820-10-7) + [Ni(trans-rac-N,N'-bis(2-mercapto-2-methylprop-1-yl)-1,2-cyclohexanediamine)]*NaPF6 → [(Ni(trans-rac-N,N'-bis(2-mercapto-2-methylprop-1-yl)-1,2-cyclohexanediamine))(Cu(OPh)(PPh3))2]

Guidance literature:

In toluene; under N2; soln. of Cu complex in toluene added to suspn. of Ni complex (molar ratio 1:1) in toluene; stirred for 5 h; filtered; hexane vapor-diffused into filtrate; crystals washed with ether; dried;

DOI:10.1021/ic040055s

upstream raw materials:

tris(triphenylphosphino)copper(I) chloride

sodium phenoxide

Downstream raw materials:

tris(triphenylphosphane)(trifluoromethyl)copper(I)

Refernces