Sodium 3-nitrobenzoate

Base Information

• Chemical Name: Sodium 3-nitrobenzoate
• CAS No.: 827-95-2
• Molecular Formula: C7H5NO4.Na
• Molecular Weight: 189.103
• Hs Code.: 2916.39
• Mol file: 827-95-2.mol

Synonyms:Benzoicacid, 3-nitro-, sodium salt (9CI);Benzoic acid, m-nitro-, sodium salt (8CI);Sodium m-nitrobenzoate;

Chemical Property of Sodium 3-nitrobenzoate

Chemical Property:

• Appearance/Colour: yellowish crystalline powder
• Vapor Pressure: 0.000139mmHg at 25°C
• Melting Point: >300 °C
• Refractive Index: 1.492
• Boiling Point: 340.7 °C at 760 mmHg
• Flash Point: 157.5 °C
• PSA: 85.95000
• Density: 1.13g/cm³
• LogP: 0.48150
• Storage Temp.: Store below +30°C.
• Solubility.: 10.9g/l
• Water Solubility.: Soluble in water.

Purity/Quality:

99% ^*data from raw suppliers

Sodium 3-nitrobenzoate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F,Xi
• Hazard Codes: F,Xi
• Statements: 11-36/37/38-22
• Safety Statements: 16-26-36-36/37-22

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Sodium 3-nitrobenzoate is an important organic intermediate. It can be used in agrochemical, pharmaceutical and dyestuff field.

Technology Process of Sodium 3-nitrobenzoate

There total 4 articles about Sodium 3-nitrobenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-acetoxy-1-(3-nitrophenyl)ethanone (90945-65-6) + sodium methylate (124-41-4) → Dimethyl ether (115-10-6,157621-61-9) + acetic acid methyl ester (79-20-9) + sodium m-nitrobenzoate (827-95-2)

Guidance literature:

In methanol; at 30 ℃; Rate constant; Mechanism; other temperature (10 to 30 deg C);

Reference yield:

3-nitro-benzaldehyde (99-61-6) → sodium m-nitrobenzoate (827-95-2)

Guidance literature:

With sodium hydroxide; sodium periodate; ruthenium trichloride; In water; at 35 ℃; Rate constant; Mechanism; other temperatures; dependence on the concentration of substrate;

Reference yield:

3-nitrobenzoic acid (121-92-6) → sodium m-nitrobenzoate (827-95-2)

Guidance literature:

With sodium hydroxide;

DOI:10.1080/15533174.2012.680096

upstream raw materials:

2-acetoxy-1-(3-nitrophenyl)ethanone

sodium methylate

3-Nitro-benzoic acid 9H-fluoren-9-ylmethyl ester

3-nitro-benzaldehyde

Downstream raw materials:

prop-2-yn-1-yl 3-nitrobenzoate

(3-Nitrobenzoyloxy)essigsaeure

benzenesulfonic acid-(3-nitro-benzyl ester)

N-(3-nitrobenzoyl)-N-phenylbenzamide

Refernces

• 1、 Morozov, A. A.. "CLEAVAGE OF THE PHENACYL ESTERS OF CARBOXYLIC AND THIOCARBOXYLIC ACIDS BY METAL ALKOXIDES". . p. 1138 - 1143. Retrieved 2007/10/02.
• 2、 Radhakrishnamurti, P. S.,Misra, P. C.. "Kinetics and Mechanism of Ru(III)-catalysed Oxidation of Aromatic Aldehydes by Sodium Metaperiodate in Alkaline Medium: A Change in Mechanism from Hydride Loss in Acid Medium to Proton Loss in Alkaline Medium". . p. 427 - 430. Retrieved 2007/10/02.