1-dimethylphenylsilyl-6,10-dimethyl-2-vinyl-1,5,9-undecatriene

Base Information

• Chemical Name: 1-dimethylphenylsilyl-6,10-dimethyl-2-vinyl-1,5,9-undecatriene
• CAS No.: 87513-97-1
• Molecular Formula: C₂₃H₃₄Si
• Molecular Weight: 338.608
• Mol file: 87513-97-1.mol

Synonyms:1-dimethylphenylsilyl-6,10-dimethyl-2-vinyl-1,5,9-undecatriene

Chemical Property of 1-dimethylphenylsilyl-6,10-dimethyl-2-vinyl-1,5,9-undecatriene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-dimethylphenylsilyl-6,10-dimethyl-2-vinyl-1,5,9-undecatriene

There total 1 articles about 1-dimethylphenylsilyl-6,10-dimethyl-2-vinyl-1,5,9-undecatriene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Vinyl bromide (593-60-2,25951-54-6) + (E)-6,10-dimethyl-5,9-undecadien-1-yne (22850-55-1) → 1-dimethylphenylsilyl-6,10-dimethyl-2-vinyl-1,5,9-undecatriene (87513-97-1)

Guidance literature:

With bis(triphenylphosphine)nickel(II) chloride; copper(l) iodide; Multistep reaction; 1.) silylmagnesation;

DOI:10.1016/S0040-4039(00)88048-X

Reference yield: 85.0%

1-dimethylphenylsilyl-6,10-dimethyl-2-vinyl-1,5,9-undecatriene (87513-97-1) → (E)-β-farnesene (18794-84-8)

Guidance literature:

With tetrabutyl ammonium fluoride; In tetrahydrofuran; dimethyl sulfoxide; at 80 ℃; for 0.5h;

DOI:10.1016/S0040-4020(01)96677-3

upstream raw materials:

Vinyl bromide

(E)-6,10-dimethyl-5,9-undecadien-1-yne

Downstream raw materials:

(E)-β-farnesene

Refernces