[1,1'-Biphenyl]-3,3',4,4'-tetracarboxylic acid

Base Information

• Chemical Name: [1,1'-Biphenyl]-3,3',4,4'-tetracarboxylic acid
• CAS No.: 22803-05-0
• Molecular Formula: C16H10O8
• Molecular Weight: 330.251
• Hs Code.: 2917399090
• European Community (EC) Number: 878-410-1
• DSSTox Substance ID: DTXSID60353943
• Nikkaji Number: J21.944D
• Wikidata: Q72443758
• Mol file: 22803-05-0.mol

Synonyms:22803-05-0;[1,1'-Biphenyl]-3,3',4,4'-tetracarboxylic acid;3,3',4,4'-Biphenyltetracarboxylic acid;4-(3,4-dicarboxyphenyl)phthalic Acid;biphenyl-3,3',4,4'-tetracarboxylic acid;3,4,3',4'-biphenyltetracarboxylic acid;4,4'-Biphthalic acid;Oprea1_718423;SCHEMBL33365;YSWG142;[1,1'-Biphenyl]-3,3',4,4'-tetracarboxylicacid;DTXSID60353943;HMS1607C04;MFCD00496632;STL196659;AKOS001483285;3,3 inverted exclamation mark ,4,4 inverted exclamation mark -Biphenyl tetracarboxylic acid;3,3',4,4' biphenyltetracarboxylic acid;AC-18961;AS-15093;SY010201;B6179;CS-0060343;EU-0000097;FT-0657451;F20572;1,1'-biphenyl-3,3',4,4'-tetracarboxylic acid;A816364;SR-01000078317;SR-01000078317-1;[1,1'-Biphenyl]-3,3',4,4'-tetracarboxylicacid, 97%;3,3 inverted exclamation mark ,4,4 inverted exclamation mark -Biphenyltetracarboxylic Acid

Chemical Property of [1,1'-Biphenyl]-3,3',4,4'-tetracarboxylic acid

Chemical Property:

• Melting Point: >300 C
• Boiling Point: 673.3 °C at 760 mmHg
• PKA: 2.80±0.10(Predicted)
• Flash Point: 375 °C
• PSA: 149.20000
• Density: 1.612 g/cm³
• LogP: 2.14640
• Storage Temp.: Sealed in dry,Room Temperature
• XLogP3: 1.7
• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 5
• Exact Mass: 330.03756727
• Heavy Atom Count: 24
• Complexity: 494

Purity/Quality:

[1,1'-Biphenyl]-3,3',4,4'-tetracarboxylicacid 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=C(C=C1C2=CC(=C(C=C2)C(=O)O)C(=O)O)C(=O)O)C(=O)O

Technology Process of [1,1'-Biphenyl]-3,3',4,4'-tetracarboxylic acid

There total 31 articles about [1,1'-Biphenyl]-3,3',4,4'-tetracarboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.2%

C22H22O6 → 4,4'-biphthalic acid (22803-05-0)

Guidance literature:

With pyridine; potassium permanganate; water; at 85 - 95 ℃; Reagent/catalyst;

Reference yield: 72.1%

C22H18O6 → 4,4'-biphthalic acid (22803-05-0)

Guidance literature:

With pyridine; potassium permanganate; water; at 85 - 95 ℃;

Reference yield: 70.9%

C24H26O6 → 4,4'-biphthalic acid (22803-05-0)

Guidance literature:

With pyridine; potassium permanganate; water; at 85 - 95 ℃;

upstream raw materials:

3,3′-dimethylbiphenyl-4,4′-dicarboxylic acid

3,3',4,4'-biphenyltetracarboxylic acid tetramethyl ester

4-iodophthalic acid

dimethyl 4-iodophthalate

Downstream raw materials:

biphenyl

3,3',4,4'-biphenyltetracarboxylic anhydride

Refernces

• 1、 -. "Preparation and separation method of biphenyldianhydride isomer". Paragraph 0028; 0031. . Retrieved 2021/10/05.
• 2、 -. "Method for preparing biphenyldianhydride through microwave-assisted catalytic coupling". Paragraph 0027; 0029; 0033; 0035-0036; 0038. . Retrieved 2021/11/06.