N-tert-butyliminoaniline

Base Information

• Chemical Name: N-tert-butyliminoaniline
• CAS No.: 131559-05-2
• Molecular Formula: C₁₁H₁₅N
• Molecular Weight: 161.247
• Mol file: 131559-05-2.mol

Synonyms:N-tert-butyliminoaniline

Chemical Property of N-tert-butyliminoaniline

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-tert-butyliminoaniline

There total 1 articles about N-tert-butyliminoaniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

pivalaldehyde (630-19-3) + aniline (62-53-3) → N-tert-butyliminoaniline (131559-05-2)

Guidance literature:

In benzene; for 24h; Heating;

DOI:10.1039/b402409e

Reference yield: 94.0%

N-tert-butyliminoaniline (131559-05-2) + trimethylsilylacetylene (1066-54-2) → N-(4,4-dimethyl-1-(trimethylsilyl)pent-1-yn-3-yl)benzeneamine

Guidance literature:

With bromotricarbonyl(tetrahydrofuran)rhenium(I) dimer; at 25 ℃; for 24h;

DOI:10.1246/cl.2006.1376

Reference yield: 90.0%

diazoacetic acid ethyl ester (623-73-4) + N-tert-butyliminoaniline (131559-05-2) → 3-tert-Butyl-1-phenyl-aziridine-2-carboxylic acid ethyl ester + Diethyl maleate (141-05-9)

Guidance literature:

copper(II) bis(trifluoromethanesulfonate); In dichloromethane; at -25 ℃;

DOI:10.1039/c39950001401

upstream raw materials:

pivalaldehyde

aniline

Downstream raw materials:

C₃₄H₄₂N₂OSSi

C₃₄H₄₂N₂OSSi

diethyl hydrazodicarboxylate

carbamic acid, phenyl-, 1-methylethyl ester

Refernces

• 1、 Surya Prakash,Mogi, Ryo,Olah, George A.. "Preparation of tri- and difluoromethylated amines from aldimines using (trifluoromethyl)trimethylsilane". . p. 3589 - 3592. Retrieved 2007/10/03.
• 2、 Derdau,Snieckus. "Condensation of laterally lithiated o-methyl and o-ethyl benzamides with imines mediated by (-)-sparteine. Enantioselective synthesis of tetrahydroisoquinolin-1-ones". . p. 1992 - 1998. Retrieved 2007/10/03.