C₁₂H₆N₂(C₆H₄O(CH₂)3C₁₅H₉N₃CH₃)2

Base Information

• Chemical Name: C₁₂H₆N₂(C₆H₄O(CH₂)3C₁₅H₉N₃CH₃)2
• CAS No.: 182284-10-2
• Molecular Formula: C₆₂H₅₀N₈O₂
• Molecular Weight: 939.131
• Mol file: 182284-10-2.mol

Synonyms:C₁₂H₆N₂(C₆H₄O(CH₂)3C₁₅H₉N₃CH₃)2

Chemical Property of C₁₂H₆N₂(C₆H₄O(CH₂)3C₁₅H₉N₃CH₃)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₁₂H₆N₂(C₆H₄O(CH₂)3C₁₅H₉N₃CH₃)2

There total 2 articles about C₁₂H₆N₂(C₆H₄O(CH₂)3C₁₅H₉N₃CH₃)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

2,9-bis(4-hydroxyphenyl)-1,10-phenanthroline (88498-43-5) + 5-(3-methanosulfonyl-1-propyl)-5-methyl-2,2':6',2-terpyridine (182803-02-7) → C12H6N2(C6H4O(CH2)3C15H9N3CH3)2 (182284-10-2)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; at 80 ℃; for 16h;

DOI:10.1021/ja963955j

Reference yield:

5,5''-dimethyl-2,2':6',2''-terpyridine (158589-14-1) → C12H6N2(C6H4O(CH2)3C15H9N3CH3)2 (182284-10-2)

Guidance literature:

Multi-step reaction with 4 steps

1.1: LDA / tetrahydrofuran / 2.5 h / -78 - 0 °C

1.2: 44 percent / tetrahydrofuran / 16 h / -78 - 20 °C

2.1: 85 percent / HCl / ethanol / 3 h / Heating

3.1: 95 percent / NEt₃ / CH₂Cl₂ / 4 h / -5 - -2 °C

4.1: 88 percent / K₂CO₃ / dimethylformamide / 16 h / 80 °C

With hydrogenchloride; potassium carbonate; triethylamine; lithium diisopropyl amide; In tetrahydrofuran; ethanol; dichloromethane; N,N-dimethyl-formamide; 1.1: Metallation / 1.2: Alkylation / 2.1: Hydrolysis / 3.1: Esterification / 4.1: Alkylation;

DOI:10.1021/ja963955j

Reference yield: 75.0%

tetrakis(acetonitrile)copper(I)tetrafluoroborate + ((C2H4O)2C6H4)NC5H2C2H2C5H2N(C6H4(C2H4O)2)OC2H4O (90030-13-0) + C12H6N2(C6H4O(CH2)3C15H9N3CH3)2 (182284-10-2) → Cu((C2H4O)5OC6H4C12H6N2C6H4)(C12H6N2(C6H4O(CH2)3C15H9N3CH3)2)(1+)*BF4(1-)=[Cu(C34H34N2O6)(C12H6N2C50H44N6O2)]BF4

Guidance literature:

In dichloromethane; acetonitrile; (ar); stirring (23°C, 30 min)of copper complex and macrocycle, addn. of bifuncional ligand, stirring (23°C, 3 h); evapn. of the solvent; chromatography;

DOI:10.1021/ja963955j

upstream raw materials:

2,9-bis(4-hydroxyphenyl)-1,10-phenanthroline

5-(3-methanosulfonyl-1-propyl)-5-methyl-2,2':6',2-terpyridine

5,5''-dimethyl-2,2':6',2''-terpyridine

Downstream raw materials:

Cu(CH₃OC₆H₄C₁₂H₆N₂C₅H₃NCH₃)2⁽¹⁺⁾*PF₆^(1-)=[Cu(CH₃OC₆H₄C₁₂H₆N₂C₅H₃NCH₃)2]PF₆

Cu(C₆₂H₅₀N₈O₂)(C₃₄H₃₄N₂O₆)⁽¹⁺⁾*BF₄^(1-) = [Cu(C₆₂H₅₀N₈O₂)(C₃₄H₃₄N₂O₆)]BF₄

Refernces

• 1、 Cardenas, Diego J.,Gavina, Pablo,Sauvage, Jean-Pierre. "A rotaxane with two Ru(terpy)2 derivatives as stoppers". . p. 1915 - 1916. Retrieved 2007/10/03.