Tartaric acid dihydrazide

Base Information

• Chemical Name: Tartaric acid dihydrazide
• CAS No.: 54789-92-3
• Molecular Formula: C₄H₁₀N₄O₄
• Molecular Weight: 178.148
• Hs Code.: 2928000090
• European Community (EC) Number: 259-349-4
• Nikkaji Number: J326.690G
• Wikidata: Q72509452
• Mol file: 54789-92-3.mol

Synonyms:tartaric acid dihydrazide

Chemical Property of Tartaric acid dihydrazide

Chemical Property:

• Vapor Pressure: 2.92E-24mmHg at 25°C
• Melting Point: 184 °C
• Refractive Index: 1.608
• Boiling Point: 724.9 °C at 760 mmHg
• Flash Point: 392.2 °C
• PSA: 150.70000
• Density: 1.626 g/cm³
• LogP: -2.12960
• XLogP3: -3.9
• Hydrogen Bond Donor Count: 6
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 3
• Exact Mass: 178.07020481
• Heavy Atom Count: 12
• Complexity: 164

Purity/Quality:

99% ^*data from raw suppliers

2,3-Dihydroxysuccinohydrazide ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C(C(=O)NN)O)(C(=O)NN)O
• Isomeric SMILES: [C@@H]([C@H](C(=O)NN)O)(C(=O)NN)O
• Uses: trifunctional amine reactive cross-linking reagent

Technology Process of Tartaric acid dihydrazide

There total 6 articles about Tartaric acid dihydrazide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

(R,R)-(+)-tartaric acid N,N'-dimethyldiamide (38115-91-2) → (2R,3R)-2,3-dihydroxybutanedihydrazide (76585-39-2,80081-45-4,80081-47-6,80081-49-8,54789-92-3)

Guidance literature:

With hydrazine hydrate; for 1h;

DOI:10.1007/s10600-013-0708-8

Reference yield: 96.0%

diethyl (2R,3R)-tartrate (87-91-2) → (2R,3R)-2,3-dihydroxybutanedihydrazide (76585-39-2,80081-45-4,80081-47-6,80081-49-8,54789-92-3)

Guidance literature:

With hydrazine; In ethanol; water; Heating / reflux;

Reference yield:

dimethyl L-tartrate (608-68-4) → (2R,3R)-2,3-dihydroxybutanedihydrazide (76585-39-2,80081-45-4,80081-47-6,80081-49-8,54789-92-3)

Guidance literature:

With hydrazine hydrate; In methanol; at 70 ℃; for 7h;

DOI:10.1039/c4cc02591a

upstream raw materials:

dimethyl tartrate

Diethyl tartrate

tartaric acid

diethyl (2R,3R)-tartrate

Downstream raw materials:

C₂₂H₂₂N₄O₄

tartaric-bis(p-nitrophenyl)hydrazone

Refernces

• 1、 Ren, Shujing,Sun, Panpan,Wu, Aoli,Sun, Na,Sun, Lixin,Dong, Bin,Zheng, Liqiang. "Ultra-fast self-healing PVA organogels based on dynamic covalent chemistry for dye selective adsorption". . p. 7701 - 7707. Retrieved 2019.
• 2、 Sun, Panpan,Ren, Shujing,Wu, Aoli,Sun, Na,Shi, Lijuan,Zheng, Liqiang. "Chirality transfer based on dynamic covalent chemistry: From small chiral molecules to supramolecules". supporting information. p. 9861 - 9864. Retrieved 2019/08/20.