1H-Imidazole, 2-(2-chlorophenyl)-1-[2-(2-chlorophenyl)-4,5-diphenyl-2H-imidazol-2-yl]-4,5-diphenyl-

Base Information

• Chemical Name: 1H-Imidazole, 2-(2-chlorophenyl)-1-[2-(2-chlorophenyl)-4,5-diphenyl-2H-imidazol-2-yl]-4,5-diphenyl-
• CAS No.: 7189-82-4
• Deprecated CAS: 1196413-86-1,947726-91-2,160307-14-2,1651214-72-0,947726-91-2
• Molecular Formula: C42H28Cl2N4
• Molecular Weight: 659.617
• Hs Code.: 29339900
• European Community (EC) Number: 230-555-6
• DSSTox Substance ID: DTXSID5074929
• Nikkaji Number: J60.924B
• Mol file: 7189-82-4.mol

Synonyms:7189-82-4;2,2'-Bis(2-chlorophenyl)-4,4',5,5'-tetraphenyl-1,2'-biimidazole;2,2'-bis(2-chlorophenyl)-4,4',5,5'-tetraphenyl-2'h-1,2'-biimidazole;1H-Imidazole, 2-(2-chlorophenyl)-1-[2-(2-chlorophenyl)-4,5-diphenyl-2H-imidazol-2-yl]-4,5-diphenyl-;C42H28Cl2N4;2,2-Bis(2-chlorophenyl)-4,4,5,5-tetraphenyl-1,2-biimidazole;EINECS 230-555-6;MFCD09028023;2-(2-chlorophenyl)-1-[2-(2-chlorophenyl)-4,5-diphenylimidazol-2-yl]-4,5-diphenylimidazole;2,2'-Bis(2-chlorophenyl)-4,4'5,5'-tetraphenyl-1,2'-biimidazole;2-(2-Chlorophenyl)-1-(2-(2-chlorophenyl)-4,5-diphenyl-2H-imidazol-2-yl)-4,5-diphenyl-1H-imidazole;1H-Imidazole, 2-(2-chlorophenyl)-1-(2-(2-chlorophenyl)-4,5-diphenyl-2H-imidazol-2-yl)-4,5-diphenyl-;2-(2-chlorophenyl)-1-[2-(2-chlorophenyl)-4,5-diphenyl-2H-imidazol-2-yl]-4,5-diphenyl-1H-imidazole;6143-80-2;Photocure 900;SCHEMBL307038;DTXSID5074929;AKOS015896133;AC-16733;AS-17693;SY053318;B1225;CS-0373828;FT-0652489;D97685;METHYL3-AMINO-4-ETHYLTHIOPHENE-2-CARBOXYLATE;W-104506;W-107882;2,2'-bis(o-chlorophenyl)-4,4',5,5'-tetraphenyl-1,2'-biimidazole;2,2'-Bis(2-dichlorophenyl)-4,4'5,5'-tetraphenyl-1,2'-biimidazole;2,2'-Bis(o-chlorophenyl)-4,4',5,5'-tetraphenyl-1,2'-bi(iii-imidazole);2,2\'-Bis(2-chlorophenyl)-4,4\',5,5\'-tetraphenyl-1,2\'-biimidazole;2,2 inverted exclamation mark -Bis(2-chlorophenyl)-4,4 inverted exclamation mark ,5,5 inverted exclamation mark -tetraphenyl-2 inverted exclamation mark H-1,2 inverted exclamation mark -biimidazole

Chemical Property of 1H-Imidazole, 2-(2-chlorophenyl)-1-[2-(2-chlorophenyl)-4,5-diphenyl-2H-imidazol-2-yl]-4,5-diphenyl-

Chemical Property:

• Vapor Pressure: 0-0Pa at 20-25℃
• Melting Point: 194 °C
• Boiling Point: 810.3 °C at 760 mmHg
• PKA: 3.37±0.10(Predicted)
• Flash Point: 443.9 °C
• PSA: 42.54000
• Density: 1.24 g/cm³
• LogP: 9.71290
• XLogP3: 10.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 7
• Exact Mass: 658.1691023
• Heavy Atom Count: 48
• Complexity: 1080

Purity/Quality:

99% ^*data from raw suppliers

2,2''-Bis(2-chlorophenyl)-4,4'',5,5''-tetraphenyl-1,2''-biimidazole ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C2=C(N(C(=N2)C3=CC=CC=C3Cl)C4(N=C(C(=N4)C5=CC=CC=C5)C6=CC=CC=C6)C7=CC=CC=C7Cl)C8=CC=CC=C8
• Uses: 2,2''-Bis(2-chlorophenyl)-4,4'',5,5''-tetraphenyl-1,2''-biimidazole (CAS# 7189-82-4) is a hexaarylbiimidazole (HABI), a visible light thiol-ene photoinitiator, such as in the polymerization of 1,6-hexanediol diacrylate by hexaarylbisimidazoles and heterocyclic mercapto compounds.

Technology Process of 1H-Imidazole, 2-(2-chlorophenyl)-1-[2-(2-chlorophenyl)-4,5-diphenyl-2H-imidazol-2-yl]-4,5-diphenyl-

There total 4 articles about 1H-Imidazole, 2-(2-chlorophenyl)-1-[2-(2-chlorophenyl)-4,5-diphenyl-2H-imidazol-2-yl]-4,5-diphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.0%

C21H13Cl3N2 (1169497-22-6) + 2-(2-chlorophenyl)-4,5-diphenyl-1H-imidazole (1707-67-1,6143-80-2) → C42H26Cl4N4 (1169497-24-8) + C42H26Cl4N4 (1169497-23-7) + C42H24Cl6N4 (1169497-25-9) + 2,2'-di(ortho-chlorophenyl)-4,4',5,5'-tetraphenyl-2'H-1,2'-biimidazole (7189-82-4)

Guidance literature:

With potassium hydroxide; potassium hexacyanoferrate(III); In water; benzene; Inert atmosphere; Darkness;

DOI:10.1039/b823277f

Reference yield:

C21H16ClN2 (29897-74-3) → 2,2'-di(ortho-chlorophenyl)-4,4',5,5'-tetraphenyl-2'H-1,2'-biimidazole (7189-82-4)

Guidance literature:

at 20 ℃; Darkness;

DOI:10.1039/b919180a

Reference yield:

2-(2'-Chlorphenyl-4,5-diphenylimidazolyl-Radikal (29897-74-3) → 2,2'-di(ortho-chlorophenyl)-4,4',5,5'-tetraphenyl-2'H-1,2'-biimidazole (7189-82-4)

Guidance literature:

In dimethyl sulfoxide; at 23.84 ℃; Solvent; Temperature; Thermodynamic data; Kinetics; Darkness;

DOI:10.1002/cphc.201300098

upstream raw materials:

C₂₁H₁₃Cl₃N₂

2-(2-chlorophenyl)-4,5-diphenyl-1H-imidazole

C₂₁H₁₆ClN₂

2-(2'-Chlorphenyl-4,5-diphenylimidazolyl-Radikal

Downstream raw materials:

C₂₁H₁₆ClN₂

lophine

3-[2-(4,5-diphenyl-1H-imidazol-2-yl)phenylthio]-4H-1,2,4-triazole

2-(2-chlorophenyl)-4,5-diphenyl-imidazol-1-ylium

Refernces

• 1、 Kikuchi, Azusa,Harada, Yukari,Yagi, Mikio,Ubukata, Takashi,Yokoyama, Yasushi,Abe, Jiro. "Photoinduced diffusive mass transfer in o-Cl-HABI amorphous thin films". body text. p. 2262 - 2264. Retrieved 2010/07/08.