Technology Process of C27H23NO3
There total 6 articles about C27H23NO3 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; 1,3-bis-(diphenylphosphino)propane;
In
1,2-dichloro-ethane; toluene;
at 150 ℃;
for 24h;
Inert atmosphere;
DOI:10.1002/anie.201005767
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 2,6-diethylaniline / 3 h / 230 °C
2: dmap; dicyclohexyl-carbodiimide / dichloromethane / Reflux
3: bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; 1,3-bis-(diphenylphosphino)propane / 1,2-dichloro-ethane; toluene / 24 h / 150 °C / Inert atmosphere
With
dmap; 2,6-diethylaniline; bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; 1,3-bis-(diphenylphosphino)propane; dicyclohexyl-carbodiimide;
In
dichloromethane; 1,2-dichloro-ethane; toluene;
1: Claisen rearrangement;
DOI:10.1002/anie.201005767
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: n-butyllithium / diethyl ether; hexane / 2 h / -78 °C / Inert atmosphere
1.2: pH 3 / Inert atmosphere
2.1: dmap; dicyclohexyl-carbodiimide / dichloromethane / Reflux
3.1: bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; 1,3-bis-(diphenylphosphino)propane / 1,2-dichloro-ethane; toluene / 24 h / 150 °C / Inert atmosphere
With
dmap; n-butyllithium; bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; 1,3-bis-(diphenylphosphino)propane; dicyclohexyl-carbodiimide;
In
diethyl ether; hexane; dichloromethane; 1,2-dichloro-ethane; toluene;
DOI:10.1002/anie.201005767