2-(Morpholinodithio)benzothiazole

Base Information

• Chemical Name: 2-(Morpholinodithio)benzothiazole
• CAS No.: 95-32-9
• Deprecated CAS: 1214747-86-0
• Molecular Formula: C11H12N2OS3
• Molecular Weight: 284.427
• Hs Code.: 2934999090
• European Community (EC) Number: 202-410-7
• NSC Number: 519695
• UNII: 8IC2AN7P63
• DSSTox Substance ID: DTXSID2026573
• Nikkaji Number: J21.247D
• Wikidata: Q26841302
• ChEMBL ID: CHEMBL3186081
• Mol file: 95-32-9.mol

Synonyms:95-32-9;2-(Morpholinodithio)benzothiazole;4-(2-Benzothiazolyldithio)morpholine;Morfax;Vulcuren 2;Sulfenax mob;Disulfal MG;Nocceler MDB;Accel DS;Benzothiazole, 2-(4-morpholinyldithio)-;Morpholino 2-benzothiazolyl disulfide;Benzothiazole, 2-(morpholinodithio)-;2-(4-MORPHOLINYLDITHIO)BENZOTHIAZOLE;2-(4-Morpholinodithio)benzothiazole;4-Morpholinyl 2-benzothiazyl disulfide;N-Morpholinyl-2-benzothiazolyl disulfide;2-Benzothiazolyl morpholino disulfide;2-Morpholinodithiobenzothiazole;4-Morpholinyl-2-benzothiazyl disulfide;Benzothiazole 2-(4-morpholinyl);4-(Benzo[d]thiazol-2-yldisulfanyl)morpholine;4-(1,3-benzothiazol-2-yldisulfanyl)morpholine;NSC 519695;Benzothiazole, 2-(4-morpholinyldithio);HSDB 5289;2-(morpholin-4-yldithio)-1,3-benzothiazole;EINECS 202-410-7;BRN 0222552;UNII-8IC2AN7P63;AI3-27133;8IC2AN7P63;DTXSID2026573;NSC-519695;DTXCID906573;CAS-95-32-9;Vulcuren-2;ACCELERATOR 26;SCHEMBL637062;CHEMBL3186081;2-(4-Morpholinyldithio)benzthiazole;Tox21_201340;Tox21_303278;C11-H12-N2-O-S3;MFCD00059033;NSC519695;2-(4-morpholinyldithio)-benzothiazole;AKOS015889084;4-Morpholinyl 2-benzothiazole disulfide;Benzothiazole, 2-(4-morpholinodithio)-;NCGC00249028-01;NCGC00257170-01;NCGC00258892-01;LS-40802;4-(2-BENZOTHIAZOLDITHIO)MORPHOLINE;N-(2-BENZOTHIAZOLYLDITHIO)MORPHOLINE;WLN: T56 BN DSJ CS- AT6 AN DOTJ;B1349;FT-0608682;D88787;2-(morpholin-4-yldisulfanyl)-1,3-benzothiazole;2-BENZOTHIAZOLYL 4-MORPHOLINYL DISULFIDE;2-(4-Morpholinyldisulfanyl)-1,3-benzothiazole #;2-BENZOTHIAZOLYL MORPHOLINO DISULFIDE [HSDB];W-109358;N-(4-MORPHOLINYL) 2-BENZOTHIAZOLYL DISULFIDE;Q26841302

Chemical Property of 2-(Morpholinodithio)benzothiazole

Chemical Property:

• Vapor Pressure: 1.16E-05mmHg at 25°C
• Melting Point: 130 °C
• Refractive Index: 1.599
• Boiling Point: 455.003 °C at 760 mmHg
• PKA: -0.46±0.10(Predicted)
• Flash Point: 228.978 °C
• PSA: 104.20000
• Density: 1.46 g/cm³
• LogP: 3.22170
• XLogP3: 3.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 3
• Exact Mass: 284.01117653
• Heavy Atom Count: 17
• Complexity: 251

Purity/Quality:

99% ^*data from raw suppliers

4-(2-Benzothiazolyldithio)morpholine >95.0%(N) ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Plastics & Rubber -> Rubber Additives
• Canonical SMILES: C1COCCN1SSC2=NC3=CC=CC=C3S2

Technology Process of 2-(Morpholinodithio)benzothiazole

There total 6 articles about 2-(Morpholinodithio)benzothiazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.8%

morpholine (110-91-8,99108-56-2) + 2-Mercaptobenzothiazole (149-30-4,118090-09-8) → 2-morpholin-4-yldisulfanyl-benzothiazole (95-32-9)

Guidance literature:

With hydrogen sulfide; sodium carbonate; In isopropyl alcohol;

Reference yield: 90.1%

2-Mercaptobenzothiazole (149-30-4,118090-09-8) → 2-morpholin-4-yldisulfanyl-benzothiazole (95-32-9)

Guidance literature:

In methanol; water;

Reference yield: 84.5%

morpholine (110-91-8,99108-56-2) + Cu(II) acetate + 2-Mercaptobenzothiazole (149-30-4,118090-09-8) → 2-morpholin-4-yldisulfanyl-benzothiazole (95-32-9)

Guidance literature:

With hydrogen sulfide; In methanol;

upstream raw materials:

N,N'-thiodimorpholine

2-thioxo-3H-1,3-benzothiazole

4,4'-dithiodimorpholine

morpholine

Refernces

• 1、 -. "Process of preparing an amino thiazolyl disulfide using a water soluble salt in combination with wet 2,2-dithiobis(benzothiazole)". . . Retrieved 2008/06/13.
• 2、 D'AMICO JJ,MORITA E. "Rubber chemicals from cyclic amines- 6". . p. 898 - 903. Retrieved 2007/10/08.