Haloxyfop-etotyl

Base Information

• Chemical Name: Haloxyfop-etotyl
• CAS No.: 87237-48-7
• Deprecated CAS: 126518-70-5
• Molecular Formula: C₁₉H₁₉ClF₃NO₅
• Molecular Weight: 433.812
• European Community (EC) Number: 402-560-5,635-516-0
• UNII: 5R94XN1YLD
• DSSTox Substance ID: DTXSID9058492
• Nikkaji Number: J636.718F
• Wikidata: Q27262774
• ChEMBL ID: CHEMBL1554997
• Mol file: 87237-48-7.mol

Synonyms:Haloxyfop-etotyl;87237-48-7;Haloxyfop-2-ethoxyethyl;Gallant;Gallant 125EE;Zellek;Dowco 453EE;Haloxyfop ethoxyethyl ester;Haloxyfop-(2-ethoxyethyl);Haloxyfop-ethoxyethyl;Haloxyfop-etotyl [BSI:ISO];2-ethoxyethyl 2-[4-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxyphenoxy]propanoate;UNII-5R94XN1YLD;5R94XN1YLD;2-Ethoxyethyl 2-(4-((3-chloro-5-(trifluoromethyl)-2-pyridinyl)oxy)phenoxy)propanoate;2-Ethoxyethyl 2-(4-(3-chloro-5-trifluoromethyl-2-pyridyloxy)phenoxy)propionate;2-Ethoxyethyl 2-(4-((3-chloro-5-(trifluoromethyl)pyridin-2-yl)oxy)phenoxy)propanoate;EC 402-560-5;Haloxyfop-ethoxyethyl 10 microg/mL in Isooctane;2-ethoxyethyl 2-(4-{[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxy}phenoxy)propanoate;Propanoic acid, 2-(4-((3-chloro-5-(trifluoromethyl)-2-pyridinyl)oxy)phenoxy)-, ester;Propanoic acid, 2-(4-((3-chloro-5-(trifluoromethyl)-2-pyridinyl)oxy)phenoxy)-, 2-ethoxyethyl ester;propanoic acid, 2-[4-[[3-chloro-5-(trifluoromethyl)-2-pyridinyl]oxy]phenoxy]-, 2-ethoxyethyl ester;SCHEMBL164100;HALOXYFOP-ETOTYL [ISO];CHEMBL1554997;DTXSID9058492;CHEBI:136736;C19-H19-Cl-F3-N-O5;AKOS015963431;NCGC00166166-01;AC-19979;LS-121332;FT-0765034;Q27262774;Haloxyfop-2-ethoxyethyl, PESTANAL(R), analytical standard;2-ethoxyethyl 2-(4-(3-chloro-5-(trifluoromethyl)pyridin-2-yloxy)phenoxy)propanoate;2-ethoxyethyl 2-(4-{[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxy}phenoxy)propionate;2-ETHOXYETHYL (RS)-2-(4-(3-CHLORO-5-(TRIFLUOROMETHYL)-2-PYRIDYLOXY)PHENOXY)PROPIONATE;Propanoic acid, 2-(4-((3-chloro-5-(trifluoromethyl)-2-pyridinyl)oxy)phenoxy)-, ester (9CI)

Chemical Property of Haloxyfop-etotyl

Chemical Property:

• Vapor Pressure: 9.09E-09mmHg at 25°C
• Melting Point: 60°C
• Boiling Point: 463.4 ºC at 760 mmHg
• PKA: -1.53±0.32(Predicted)
• Flash Point: 234.1 ºC
• Density: 1.306 g/cm³
• XLogP3: 4.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 9
• Rotatable Bond Count: 10
• Exact Mass: 433.0903849
• Heavy Atom Count: 29
• Complexity: 503

Purity/Quality:

99.9% ^*data from raw suppliers

Haloxyfop-etotyl ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn,N
• Statements: 22-50/53
• Safety Statements: 22-36-60-61

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCOCCOC(=O)C(C)OC1=CC=C(C=C1)OC2=C(C=C(C=N2)C(F)(F)F)Cl

Technology Process of Haloxyfop-etotyl

There total 1 articles about Haloxyfop-etotyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

2-ethoxy-ethanol (110-80-5) + 2-fluoro-3-chloro-5-(trifluoromethyl)pyridine (72537-17-8) + (R)-2-(4-hydroxyphenoxy)propionic acid (94050-90-5) → haloxyfop-etotyl (87237-48-7)

Guidance literature:

2-fluoro-3-chloro-5-(trifluoromethyl)pyridine; (R)-2-(4-hydroxyphenoxy)propionic acid; With potassium phosphate; tetra-(n-butyl)ammonium iodide; In N,N-dimethyl-formamide; at 50 - 60 ℃; for 2h;

With 1,3,5-trichloro-2,4,6-triazine; In N,N-dimethyl-formamide; at 5 - 25 ℃; for 1.16667h;

2-ethoxy-ethanol; In N,N-dimethyl-formamide;

DOI:10.4067/S0717-97072011000400002

upstream raw materials:

2-ethoxy-ethanol

2-fluoro-3-chloro-5-(trifluoromethyl)pyridine

(R)-2-(4-hydroxyphenoxy)propionic acid

Refernces