[1,4';1',1'';4'',4''';1''',1'''';4'''',1''''']Sexiphenyl-3,2',2'',2''',2'''',3'''''-hexaol

Base Information

• Chemical Name: [1,4';1',1'';4'',4''';1''',1'''';4'''',1''''']Sexiphenyl-3,2',2'',2''',2'''',3'''''-hexaol
• CAS No.: 195737-44-1
• Molecular Formula: C₃₆H₂₆O₆
• Molecular Weight: 554.599
• Mol file: 195737-44-1.mol

Synonyms:[1,4';1',1'';4'',4''';1''',1'''';4'''',1''''']Sexiphenyl-3,2',2'',2''',2'''',3'''''-hexaol

Chemical Property of [1,4';1',1'';4'',4''';1''',1'''';4'''',1''''']Sexiphenyl-3,2',2'',2''',2'''',3'''''-hexaol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [1,4';1',1'';4'',4''';1''',1'''';4'''',1''''']Sexiphenyl-3,2',2'',2''',2'''',3'''''-hexaol

There total 3 articles about [1,4';1',1'';4'',4''';1''',1'''';4'''',1''''']Sexiphenyl-3,2',2'',2''',2'''',3'''''-hexaol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3,3'-dimethoxybiphenyl (6161-50-8) → [1,4';1',1'';4'',4''';1''',1'''';4'''',1''''']Sexiphenyl-3,2',2'',2''',2'''',3'''''-hexaol (195737-44-1)

Guidance literature:

Multi-step reaction with 3 steps

1: 4 percent / t-BuLi, I₂ / diethyl ether

2: 77 percent / Pd(PPh₃)4, Na₂CO₃

3: BBr₃

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; iodine; tert.-butyl lithium; boron tribromide; sodium carbonate; In diethyl ether;

DOI:10.1021/ja971513h

Reference yield:

3,2',2'',2''',2'''',3'''''-Hexamethoxy-[1,4';1',1'';4'',4''';1''',1'''';4'''',1''''']sexiphenyl (195737-39-4) → [1,4';1',1'';4'',4''';1''',1'''';4'''',1''''']Sexiphenyl-3,2',2'',2''',2'''',3'''''-hexaol (195737-44-1)

Guidance literature:

With boron tribromide;

DOI:10.1021/ja971513h DOI:10.1039/a708841h

Reference yield:

4,4'-diiodo-3,3'-dimethoxylbiphenyl (92160-61-7) → [1,4';1',1'';4'',4''';1''',1'''';4'''',1''''']Sexiphenyl-3,2',2'',2''',2'''',3'''''-hexaol (195737-44-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 77 percent / Pd(PPh₃)4, Na₂CO₃

2: BBr₃

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; boron tribromide; sodium carbonate;

DOI:10.1021/ja971513h

upstream raw materials:

3,2',2'',2''',2'''',3'''''-Hexamethoxy-[1,4';1',1'';4'',4''';1''',1'''';4'''',1''''']sexiphenyl

3,3'-dimethoxybiphenyl

4,4'-diiodo-3,3'-dimethoxylbiphenyl

Downstream raw materials:

C₇₂H₈₆O₁₈

Refernces

• 1、 Sakai, Naomi,Brennan, Kevin C.,Weiss, Linnea A.,Matile, Stefan. "Toward biomimetic ion channels formed by rigid-rod molecules: Length-dependent ion-transport activity of substituted oligo(p-phenylene)s". . p. 8726 - 8727. Retrieved 2007/10/03.