Bis(diethyl-D-tartrate glycolato)diboron

Base Information

• Chemical Name: Bis(diethyl-D-tartrate glycolato)diboron
• CAS No.: 312693-46-2
• Molecular Formula: C₁₆H₂₄B₂O₁₂
• Molecular Weight: 429.981
• Hs Code.: 2920907090
• DSSTox Substance ID: DTXSID30373496
• Nikkaji Number: J2.199.916D
• Wikidata: Q72444986
• Mol file: 312693-46-2.mol

Synonyms:Bis(diethyl-D-tartrate glycolato)diboron;312693-46-2;diethyl (4S,5S)-2-[(4S,5S)-4,5-bis(ethoxycarbonyl)-1,3,2-dioxaborolan-2-yl]-1,3,2-dioxaborolane-4,5-dicarboxylate;Bis(diethyl-D-tartrateglycolato)diboron;Bis(diethyl-D-tartrate glycolato) diboron;AC-4651;DTXSID30373496;AKOS015914708;A820781;J-018346;(4S,4'S,5S,5'S)-tetraethyl 2,2'-bi(1,3,2-dioxaborolane)-4,4',5,5'-tetracarboxylate;tetraethyl (4S,4'S,5S,5'S)-[2,2'-bi(1,3,2-dioxaborolane)]-4,4',5,5'-tetracarboxylate;2,2'-Bi[1,3,2-dioxaborolane]-4alpha,4'alpha,5beta,5'beta-tetracarboxylic acid tetraethyl ester

Chemical Property of Bis(diethyl-D-tartrate glycolato)diboron

Chemical Property:

• Appearance/Colour: white to light yellow crystal powder
• Vapor Pressure: 0mmHg at 25°C
• Melting Point: 40-47 °C(lit.)
• Refractive Index: 1.465
• Boiling Point: 451.234 °C at 760 mmHg
• Flash Point: 226.698 °C
• PSA: 142.12000
• Density: 1.275 g/cm³
• LogP: -1.13840
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 12
• Rotatable Bond Count: 13
• Exact Mass: 430.1453865
• Heavy Atom Count: 30
• Complexity: 538

Purity/Quality:

98%,99%, ^*data from raw suppliers

Bis(diethyl-D-tartrate glycolato)diboron ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: B1(OC(C(O1)C(=O)OCC)C(=O)OCC)B2OC(C(O2)C(=O)OCC)C(=O)OCC
• Isomeric SMILES: B1(O[C@@H]([C@H](O1)C(=O)OCC)C(=O)OCC)B2O[C@@H]([C@H](O2)C(=O)OCC)C(=O)OCC

Technology Process of Bis(diethyl-D-tartrate glycolato)diboron

There total 2 articles about Bis(diethyl-D-tartrate glycolato)diboron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

diethyl (2R,3R)-tartrate (87-91-2) → bis(diethyl-L-tartrateglycolato)diboron (312693-46-2)

Guidance literature:

With tetrakis(dimethylamido)diborane; In toluene; at 105 ℃; for 0.116667h;

Reference yield: 96.8%

→ bis(diethyl-D-tartrate glycolato)diboron (312693-46-2)

Guidance literature:

upstream raw materials:

diethyl (2R,3R)-tartrate

Refernces