bis(triphenylphosphane)iminium(pentafluorophenyl)chlorogold(I)

Base Information

• Chemical Name: bis(triphenylphosphane)iminium(pentafluorophenyl)chlorogold(I)
• CAS No.: 74558-90-0
• Molecular Formula: C₆AuClF₅*C₃₆H₃₀NP₂
• Molecular Weight: 938.066
• Mol file: 74558-90-0.mol

Synonyms:bis(triphenylphosphane)iminium(pentafluorophenyl)chlorogold(I)

Chemical Property of bis(triphenylphosphane)iminium(pentafluorophenyl)chlorogold(I)

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of bis(triphenylphosphane)iminium(pentafluorophenyl)chlorogold(I)

There total 1 articles about bis(triphenylphosphane)iminium(pentafluorophenyl)chlorogold(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

pentafluorophenyl(tetrahydrothiophene)gold(I) + bis(triphenylphosphine)iminium chloride (21050-13-5) → bis(triphenylphosphane)iminium(pentafluorophenyl)chlorogold(I) (74558-90-0)

Guidance literature:

In acetone; stirring (0.5 h); filtering, pptn. on concg. and Et2O addn., filtering, washing (Et2O), drying (N2-stream); elem. anal.;

DOI:10.1021/om970106b

Reference yield: 95.0%

bis(triphenylphosphane)iminium(pentafluorophenyl)chlorogold(I) (74558-90-0) + AuC6F5(P(C6H5)2CCH) (497064-99-0) → AuC6F5(P(C6H5)2CC)Au(C6F5)(1-)*N(P(C6H5)3)2(1+)=Au2(C6F5)2P(C6H5)2CC(N(P(C6H5)3)2) (497065-02-8)

Guidance literature:

With NaOMe; In methanol; NaOMe was added to MeOH soln. of Au(C6F5)(PPh2CCH), stirred for 2 h, Au-complex was added, stirred for 1 h under inert atm.; solvent was removed, CH2Cl2 was added, filtered, evapd. to dryness; elem. anal.;

Reference yield: 80.0%

bis(triphenylphosphane)iminium(pentafluorophenyl)chlorogold(I) (74558-90-0) + acetylene (74-86-2,25067-58-7) → Au(C6F5)C2H(1-)*((C6H5)3P)2N(1+)=Au(C6F5)C2H(((C6H5)3P)2N) (277303-32-9)

Guidance literature:

With thallium acetylacetonate; In dichloromethane; byproducts: TlCl; a soln. of Tl(acac) and Au-complex was stirred for 40 min, filtd. through Celite, C2H2 was bubbled through soln. for 30 min; filtd. through anhyd. MgSO4, concd., Et2O added, ppt. collected; elem. anal.;

DOI:10.1021/om9910322

upstream raw materials:

bis(triphenylphosphine)iminium chloride

Downstream raw materials:

gold

Au(C₆F₅)C₂H^(1-)*((C₆H₅)3P)2N⁽¹⁺⁾=Au(C₆F₅)C₂H(((C₆H₅)3P)2N)

AuC₆F₅(P(C₆H₅)2CC)Au(C₆F₅)^(1-)*N(P(C₆H₅)3)2⁽¹⁺⁾=Au₂(C₆F₅)2P(C₆H₅)2CC(N(P(C₆H₅)3)2)

PPN[Au(p-CH₃-C₆H₄-CC-S)(C₆F₅)]

Refernces