[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)

Base Information

• Chemical Name: [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)
• CAS No.: 67292-34-6
• Molecular Formula: C34H28Cl2FeNiP2
• Molecular Weight: 683.987
• Hs Code.: 29319090
• Mol file: 67292-34-6.mol

Synonyms:Ferrocene, 1,1'-bis(diphenylphosphino)-,nickel complex;(1,1'-Bis(diphenylphosphino)ferrocene)dichloronickel;1,1'-Bis(diphenylphosphino)ferrocene nickel dichloride;Dichloro(bis(diphenylphosphino)ferrocene)nickel;Dichloro[1,1'-bis(diphenylphosphino)ferrocene]nickel;Nickel,[1,1'-bis(diphenylphosphino)ferrocene-P,P']dichloro-, (T-4)-;

Chemical Property of [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)

Chemical Property:

• Melting Point: 285 °C (dec.)(lit.)
• PSA: 27.18000
• LogP: 7.76790
• Storage Temp.: Inert atmosphere,Room Temperature
• Water Solubility.: Insoluble in water.

Purity/Quality:

99% ^*data from raw suppliers

(1,1''-Bis(diphenylphosphino)ferrocene)dichloronickel(II) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T
• Hazard Codes: T
• Statements: 45-42/43
• Safety Statements: 53-22-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Uses: diphosphine 1,1'-bis(diphenylphosphino)ferrocene (dppf) are used in transition metal-catalyzed reactions to synthesize pharmaceuticals and agrochemicals. (1,1''-Bis(diphenylphosphino)ferrocene)dichloronickel(II) is an organometallic catalyst used in a variety of synthetic applications, such as the gem-?difluoropropargylation of alkylzinc reagents, or cross coupling reactions to form 2,?3,?5,?6-?tetrasubstituted dehydropiperidines. suzuki reaction

Technology Process of [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)

There total 7 articles about [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

1,1'-bis-(diphenylphosphino)ferrocene (12150-46-8) + nickel(II) chloride hexahydrate → [1,1'-bis(diphenylphosphino)ferrocene]nickel(II) chloride (67292-34-6)

Guidance literature:

In ethanol; at 80 ℃; for 0.5h; Sealed tube; Inert atmosphere;

DOI:10.1021/om500156q

Reference yield: 97.0%

→ cis-[dppf]NiCl2 (67292-34-6)

Guidance literature:

In ethanol; at 80 ℃; for 0.5h; Inert atmosphere;

Reference yield: 85.0%

1,1'-bis-(diphenylphosphino)ferrocene (12150-46-8) + nickel(II) chloride hexahydrate → cis-[dppf]NiCl2 (67292-34-6)

Guidance literature:

In ethanol; at 80 ℃; Inert atmosphere; Schlenk technique;

DOI:10.1039/d0cc06652d

upstream raw materials:

1,1'-bis-(diphenylphosphino)ferrocene

nickel dichloride

bis(triphenylphosphine)nickel(II) chloride

carbon monoxide

Downstream raw materials:

(1,1′-bis(diphenylphosphino)ferrocene)₂Ni

[Ni(S₂CN(CH₂CH=CH₂)2)(1,1'-bis(diphenylphosphino)ferrocene)]PF₆

[(1,1′-bis(diphenylphosphino)ferrocene)Ni⁽⁰⁾(1,5-cyclooctadiene)]

Refernces

• 1、 Zhang, Shaoke,Weniger, Florian,Ye, Fei,Rabeah, Jabor,Ellinger, Stefan,Zaragoza, Florencio,Taeschler, Christoph,Neumann, Helfried,Brückner, Angelika,Beller, Matthias. "Selective nickel-catalyzed fluoroalkylations of olefins". supporting information. p. 15157 - 15160. Retrieved 2020/12/21.
• 2、 -. "METHOD FOR PREPARATION OF FLUORO ALKYLATED COMPOUNDS BY HOMOGENEOUS NI CATALYSIS". Page/Page column 16-17. . Retrieved 2020/09/08.