Rhodium, carbonylhydrotris(triphenylphosphine)-, (TB-5-23)-

Base Information

• Chemical Name: Rhodium, carbonylhydrotris(triphenylphosphine)-, (TB-5-23)-
• CAS No.: 17185-29-4
• Molecular Formula: C55H46OP3Rh
• Molecular Weight: 918.796
• Hs Code.: 28439000
• UNII: 720P7594ZM
• Mol file: 17185-29-4.mol

Synonyms:Tristriphenylphosphine rhodium carbonyl hydride;C55H46OP3Rh;C55-H46-O-P3-Rh;Rhodium, carbonylhydrotris(triphenylphosphine)-, (TB-5-23)-;720P7594ZM;Carbonylhydridotris(triphenylphosphine)rhodium(I);64665-44-7;J-520009;TRIS(TRIPHENYLPHOSPHINE)RHODIUMCARBONYLHYDRIDE;trans-Carbonyl(hydrido)tris(triphenylphosphine)rhodium;TRANS-HYDRIDOCARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM;TRISTRIPHENYLPHOSPHINE RHODIUM CARBONYL HYDRIDE [MI]

Chemical Property of Rhodium, carbonylhydrotris(triphenylphosphine)-, (TB-5-23)-

Chemical Property:

• Appearance/Colour: yellow crystals
• Vapor Pressure: 0Pa at 25℃
• Melting Point: 150 °C (dec.)(lit.)
• Boiling Point: 360ºC at 760mmHg
• Flash Point: 181.7ºC
• PSA: 40.77000
• Density: 1.33
• LogP: 10.12640
• Storage Temp.: 2-8°C
• Sensitive.: Moisture Sensitive
• Solubility.: Soluble in hydrocarbons (e.g. benzene and toluene) with dissocia
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 9
• Exact Mass: 918.18165
• Heavy Atom Count: 60
• Complexity: 212

Purity/Quality:

99% ^*data from raw suppliers

Carbonylhydrotris(triphenylphosphine)rhodium ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T
• Hazard Codes: T
• Statements: 23/24/25
• Safety Statements: 36/37/39-45-36/37

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [H-].[C-]#[O+].C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Rh]
• Uses: Hydrogenation, hydrosilation, isomerization, carbonylation, hydroformylation, oxidation

Technology Process of Rhodium, carbonylhydrotris(triphenylphosphine)-, (TB-5-23)-

There total 24 articles about Rhodium, carbonylhydrotris(triphenylphosphine)-, (TB-5-23)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

trans-[(carbonyl)(carboxylato)(triphenylphosphine)2rhodium(I)] (32354-32-8) + triphenylphosphine (603-35-0) → carbonylhydridetris(triphenylphosphine)rhodium(I) (17185-29-4)

Guidance literature:

In isopropyl alcohol; byproducts: CO2; reaction carried out under dry argon; Rh-complex and triphenylphosphine placed into a reaction vessel and propanol-2 added; reaction vessel immersed into a water-bath preheated to 90°C; heated under reflux for30 min; mixture cooled to room temp.; mustard-colored crystals isolated by filtration, washed with ether, and dried in vacuo;

DOI:10.1016/j.inoche.2004.01.013

Reference yield: 89.0%

[(CO)2Rh(μ-,kappa.O,O'-HCO2)]2 (69041-48-1) + triphenylphosphine (603-35-0) → carbonylhydridetris(triphenylphosphine)rhodium(I) (17185-29-4)

Guidance literature:

In isopropyl alcohol; byproducts: CO, CO2; reaction carried out under dry argon; Rh-complex and triphenylphosphine placed into a reaction vessel and propanol-2 added; yellow precipitate formed; reaction vessel immersed into a water-bath preheated to 90°C; refluxed for 30 min; mixture cooled to room temp.; mustard-colored crystals isolated by filtration, washed with ether, and dried in vacuo; elem. anal.;

DOI:10.1016/j.inoche.2004.01.013

Reference yield: 89.0%

dirhodium di(μ-formato) tetracarbonyl (69041-48-1) + triphenylphosphine (603-35-0) → carbonylhydridetris(triphenylphosphine)rhodium(I) (17185-29-4)

Guidance literature:

In isopropyl alcohol; byproducts: CO2; under Ar, Schlenk setup, PPh3 (2.24 mmol) and Rh compd. (0.245 mmol) mixed in isoropanol, refluxed for 30 min, crystd., cooled to room temp.; filtered off, washed (Et2O), dried (vac.), elem. anal.;

DOI:10.1007/s11173-005-0008-3

upstream raw materials:

carbonyl(hydroxy)bis(triphenylphosphine)rhodium(I)

hydridotetakis(triphenylphosphine)rhodium(I)

<((E)-But-2-enyl)oxy>trimethylsilan

[(CO)2Rh(μ-,kappa.O,O'-HCO2)]2

Downstream raw materials:

HRh(CO)(DBP)3

(Cp)2(hafnium)(μ-PCy2)2(rhodium)H(CO)(PCy3)

(Cp)2(hafnium)(μ-PPh2)2(rhodium)H(CO)(PPh3)

Rh(CO)(P(C₆H₅)3)2(C₆H₅CHNNCONH₂)

Refernces

• 1、 Kameo, Hajime,Hashimoto, Yasuhiro,Nakazawa, Hiroshi. "Synthesis of iridaboratranes bearing phosphine-tethered borane: Reversible CO/PR3 (R = Me, OMe, OEt) substitution reactions induced by a σ-electron-acceptor borane ligand". . p. 4251 - 4258. Retrieved 2012.
• 2、 Treciak, A. M.,Ziolkowski, J. J.,Jaworska-Galas, Z.,Mista, W.,Wrzyszcz, J.. "Homogeneous and alumina supported rhodium complex catalyzed hydrogenation". . p. 13 - 22. Retrieved 1994.
• 3、 Khokhar, Munir D.,Shukla, Ram S.,Jasra, Raksh V.. "Hydroformylation of dihydrofurans catalyzed by rhodium complex encapsulated hexagonal mesoporous silica". . p. 1 - 6. Retrieved 2015.
• 4、 Alsalahi,Trzeciak. ""On water" hydroformylation of 1-hexene using Rh/PAA (PAA = polyacrylic acid) as catalyst". . p. 30384 - 30391. Retrieved 2014/08/05.