[Pt(PPh₃)(o-phenylenediamine)]

Base Information

• Chemical Name: [Pt(PPh₃)(o-phenylenediamine)]
• CAS No.: 64608-35-1
• Molecular Formula: C₄₂H₃₆N₂P₂Pt
• Molecular Weight: 825.789
• Mol file: 64608-35-1.mol

Synonyms:[Pt(PPh₃)(o-phenylenediamine)]

Chemical Property of [Pt(PPh₃)(o-phenylenediamine)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Pt(PPh₃)(o-phenylenediamine)]

There total 3 articles about [Pt(PPh₃)(o-phenylenediamine)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

dioxygenbis(triphenylphosphine)platinum(0) (29894-57-3) + cyclohexa-3,5-diene-1,2-diimine (4710-40-1) → [Pt(PPh3)(o-phenylenediamine)] (64608-35-1)

Guidance literature:

In ethanol; byproducts: H2O2; N2-atmosphere; pptn. on mixing and stirring (room temp.); filtration after 1 h, washing (EtOH, Et2O), drying (vac.);

DOI:10.1016/S0020-1693(00)89470-0

Reference yield:

Pt(P(C6H5)3)2((NH2)2C6H4)(2+)*2BF4(1-)*H2O=[Pt(P(C6H5)3)2((NH2)2C6H4)](BF4)2*H2O → [Pt(PPh3)(o-phenylenediamine)] (64608-35-1)

Guidance literature:

With NaHCO₃ or KOH; In diethyl ether; water; N2-atmosphere; addn. of aq. NaHCO3 or KOH to suspn. of Pt-complex in Et2O (3 h, room temp., pptn.); filtration, washing (H2O, hexane), drying (vac.);

DOI:10.1016/S0020-1693(00)89470-0

Reference yield:

[Pt(PPh3)(ortho-phenylenediamine)] * ethanol → [Pt(PPh3)(o-phenylenediamine)] (64608-35-1)

Guidance literature:

In hexane; chloroform; N2-atmosphere; room temp.; rapid crystn.; elem. anal.;

DOI:10.1016/S0020-1693(00)89470-0

upstream raw materials:

dioxygenbis(triphenylphosphine)platinum⁽⁰⁾

cyclohexa-3,5-diene-1,2-diimine

Downstream raw materials:

(benzene-1,2-diolato-O,O')bis(triphenylphosphine)platinum(II)

cis-dichlorobis(triphenylphosphine)platinum(II)