trans-chloro-bis(trimethylphosphine)(phenyl)platinum(II)

Base Information Edit

Chemical Name:trans-chloro-bis(trimethylphosphine)(phenyl)platinum(II)
CAS No.:90065-11-5
Molecular Formula:C₁₂H₂₃ClP₂Pt
Molecular Weight:459.795
Hs Code.:
Mol file:90065-11-5.mol

Synonyms:trans-chloro-bis(trimethylphosphine)(phenyl)platinum(II)

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Chemical Property of trans-chloro-bis(trimethylphosphine)(phenyl)platinum(II) Edit

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Technology Process of trans-chloro-bis(trimethylphosphine)(phenyl)platinum(II)

There total 9 articles about trans-chloro-bis(trimethylphosphine)(phenyl)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: cis-[Pt(C₆H₅)Cl(P(CH₃)3)2]

: 90065-11-5
trans-chloro-bis(trimethylphosphine)(phenyl)platinum(II)

Guidance literature:: In not given; isomerization 1 h at room temp.;
DOI:10.1021/om00113a023

Reference yield: 90.0%

: 52595-91-2,343573-63-7
cis-[Pt(C₆H₅)2(P(CH₃)3)2]

: 90065-11-5
trans-chloro-bis(trimethylphosphine)(phenyl)platinum(II)

Guidance literature:: With HCl; In diethyl ether; an ethereal sol. of dry HCl was added to equiv amount of complex in ether at -78°C, the mixt. was refluxed (Ar); evapd. at -30°C, crystd. from acetone-petroleum ether; elem. anal.;
DOI:10.1016/S0022-328X(00)00916-5

Reference yield: 85.0%

: 19471-47-7,15630-86-1,21545-76-6
cis-dichlorobis(trimethylphosphine)platinum(II)

: 2923-28-6
silver trifluoromethanesulfonate

: 143-66-8
sodium tetraphenyl borate

: 90065-11-5
trans-chloro-bis(trimethylphosphine)(phenyl)platinum(II)

Guidance literature:: With lithium chloride; In methanol; 1. cis-(PtCl2(PMe3)2) and AgCF3SO3 (2 equivalents) -> cis-(Pt(S)2(PMe3)2)(2+), with S = H2O or MeOH, detected by 31P NMR; 2. addn. of NaBPh4 -> trans-(PtPh(S)(PMe3)2)(1+), detected by 31P NMR; 3. react. with LiCl;
DOI:10.1021/om00113a023