1-Hexyl-3-methylimidazolium tetrafluoroborate

Base Information

• Chemical Name: 1-Hexyl-3-methylimidazolium tetrafluoroborate
• CAS No.: 244193-50-8
• Molecular Formula: BF₄*C₁₀H₁₉N₂
• Molecular Weight: 254.079
• Hs Code.: 29332900
• European Community (EC) Number: 680-100-4
• DSSTox Substance ID: DTXSID8049252
• ChEMBL ID: CHEMBL3184403
• Mol file: 244193-50-8.mol

Synonyms:1-hexyl-3-methylimidazolium tetrafluoroborate

Chemical Property of 1-Hexyl-3-methylimidazolium tetrafluoroborate

Chemical Property:

• Appearance/Colour: Clear yellow to orange viscous liquid
• Melting Point: -82 °C
• Refractive Index: n20/D 1.430
• PSA: 8.81000
• Density: 1.149 g/mL at 20 °C(lit.)
• LogP: 3.19290
• Storage Temp.: Inert atmosphere,Room Temperature
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 5
• Exact Mass: 254.1577414
• Heavy Atom Count: 17
• Complexity: 134

Purity/Quality:

99% ^*data from raw suppliers

1-Hexyl-3-methylimidazolium Tetrafluoroborate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 23-24/25-37/39-26

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [B-](F)(F)(F)F.CCCCCCN1C=C[N+](=C1)C

Technology Process of 1-Hexyl-3-methylimidazolium tetrafluoroborate

There total 14 articles about 1-Hexyl-3-methylimidazolium tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1-hexyl-3-methylimidazol-1-ium chloride (171058-17-6) → 1-hexyl-3-methylimidazolium tetrafluoroborate (244193-50-8)

Guidance literature:

With triethyloxonium fluoroborate; at 20 ℃; for 0.5h; Product distribution / selectivity;

Reference yield: 96.5%

lithium tetrafluoroborate + 1-hexyl-3-methyl-1-imidazolium bromide (85100-78-3) → 1-hexyl-3-methylimidazolium tetrafluoroborate (244193-50-8)

Guidance literature:

In acetone; at 20 ℃; for 30h;

Reference yield: 94.0%

1-methyl-1H-imidazole (616-47-7) + 1-bromo-hexane (111-25-1) → 1-hexyl-3-methylimidazolium tetrafluoroborate (244193-50-8)

Guidance literature:

With sodium tetrafluoroborate; 1-hexyl-3-methylimidazolium tetrafluoroborate; at 80 ℃; for 15h;

DOI:10.1055/s-2003-42420

upstream raw materials:

1-hexyl-3-methylimidazol-1-ium chloride

1-hexyl-3-methyl-1-imidazolium bromide

1-methyl-1H-imidazole

1-bromo-hexane

Refernces

• 1、 Marefat, Mohamadreza,Ahmadi, Ebrahim,Mohamadnia, Zahra. "Influence of ionic liquid counterions on activity and selectivity of ethylene trimerization using chromium-based catalysts in biphasic media". . . Retrieved 2020.
• 2、 -. "Quantum dots in which ionic liquids are ion-bonded and their preparation method". Page/Page column 16-17. . Retrieved 2021/09/01.
• 3、 Yohannes, Alula,Li, Jing,Yao, Shun. "Various metal organic frameworks combined with imidazolium, quinolinum and benzothiazolium ionic liquids for removal of three antibiotics from water". . . Retrieved 2020/10/02.