Potassium tetrachloroaurate(III)

Base Information

• Chemical Name: Potassium tetrachloroaurate(III)
• CAS No.: 13682-61-6
• Deprecated CAS: 253678-12-5
• Molecular Formula: AuCl₄*K
• Molecular Weight: 377.877
• Hs Code.: 28433000
• European Community (EC) Number: 237-190-1
• Wikidata: Q4456675
• Mol file: 13682-61-6.mol

Synonyms:Potassium tetrachloroaurate(III);13682-61-6;Potassium tetrachloroaurate;potassium;tetrachlorogold(1-);K[AuCl4];potassium tetrachloridoaurate;Potassium gold(III) chloride;Aurate(1-), tetrachloro-, potassium, (SP-4-1)-;potassium tetrachloroaurate(1-);CHEBI:51564;potassium tetrachloridoaurate(1-);potassium tetrachloridoaurate(III);Potassium gold(III) chloride, 98%;AKOS015914591;FT-0764974;Gold pound cento pound(c)potassium chloride;NS00085935;C72475;Q4456675;Aurate(1-), tetrachloro-, potassium (1:1), (SP-4-1)-;Potassium gold(III) chloride, 99.995% trace metals basis

Chemical Property of Potassium tetrachloroaurate(III)

Chemical Property:

• Appearance/Colour: yellow-orange crystalline powder
• Melting Point: 300 °C
• PSA: 0.00000
• LogP: 2.75550
• Storage Temp.: Inert atmosphere,Room Temperature
• Solubility.: H2O: soluble
• Water Solubility.: soluble
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 377.802737
• Heavy Atom Count: 6
• Complexity: 19.1

Purity/Quality:

98%,99%, ^*data from raw suppliers

Potassium tetrachloroaurate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36-37/39

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Metals -> Metals, Inorganic Compounds
• Canonical SMILES: Cl[Au-](Cl)(Cl)Cl.[K+]
• Uses: Photography, painting porcelain and glass, medicine. Key raw material for synthesis of new gold(III) dithiolate complexes for luminescence studies or possible uses as photosensitizers or photocatalysts. Key raw material for synthesis of new gold(III) dithiolate complexes for luminescence studies or possible uses as photosensitizers or photocatalysts.1

Technology Process of Potassium tetrachloroaurate(III)

There total 8 articles about Potassium tetrachloroaurate(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

gold(I) chloride (10294-29-8,11118-27-7) → potassium tetrachloroaurate(III) (13682-61-6) + potassium tetrabromoaurate(III) (14323-32-1) + gold (7440-57-5,457905-15-6)

Guidance literature:

With potassium bromide; In not given;

Reference yield:

gold (7440-57-5,457905-15-6) → potassium tetrachloroaurate(III) (13682-61-6)

Guidance literature:

With potassium chloride; In ethanol; dissolving in aq. regia; evapn.; dissolving in CH3OH; filtration;

Reference yield:

potassium chloride + gold (7440-57-5,457905-15-6) → potassium tetrachloroaurate(III) (13682-61-6)

Guidance literature:

With Oxone; In neat (no solvent); at 20 ℃; Milling;

DOI:10.1002/anie.201712602

upstream raw materials:

gold

gold(III) chloride

gold(I) chloride

Downstream raw materials:

chloro(dimethylsulfide) gold(I)

AuCl₃((C₆H₅)2C₃H₂N₂)

5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrinatogold(III)

bis[1,2-di(4-n-butyloxyphenyl)ethane-1,2-dithiolene]gold

Refernces

• 1、 Do, Jean-Louis,Tan, Davin,Fri??i?, Tomislav. "Oxidative Mechanochemistry: Direct, Room-Temperature, Solvent-Free Conversion of Palladium and Gold Metals into Soluble Salts and Coordination Complexes". supporting information. p. 2667 - 2671. Retrieved 2018/02/06.