Silver hexafluorophosphate

Base Information

• Chemical Name: Silver hexafluorophosphate
• CAS No.: 26042-63-7
• Deprecated CAS: 188916-45-2,188916-46-3,70251-05-7,2655504-69-9
• Molecular Formula: AgF6P
• Molecular Weight: 252.832
• Hs Code.: 28432900
• European Community (EC) Number: 247-428-6
• DSSTox Substance ID: DTXSID70885326
• Wikipedia: Silver hexafluorophosphate
• Wikidata: Q1876201
• Mol file: 26042-63-7.mol

Synonyms:Silver hexafluorophosphate;26042-63-7;silver;hexafluorophosphate;Phosphate(1-), hexafluoro-, silver(1+) (1:1);silver hexafluorophosphate(v);Phosphate(1-), hexafluoro-, silver(1+);Silver (I) hexafluorophosphate;silver(i) hexafluorophosphate(v);EINECS 247-428-6;Ag.F6P;Silver(I) hexafluorophosphate;MFCD00003415;AgPF6;Ag.F6-P;silver hexafluorophosphate (v);DTXSID70885326;AKOS015901908;Phosphate(1-), hexafluoro-, silver(1);FT-0696269;A818148;Q1876201

Chemical Property of Silver hexafluorophosphate

Chemical Property:

• Appearance/Colour: white to greyish-beige powder
• Melting Point: 102 °C (dec.)(lit.)
• PSA: 13.59000
• LogP: 3.38240
• Sensitive.: Moisture Sensitive
• Solubility.: Soluble in organic solvents such as benzene, toluene, and aceton
• Water Solubility.: soluble
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 0
• Exact Mass: 251.86927
• Heavy Atom Count: 8
• Complexity: 62.7

Purity/Quality:

99.9% ^*data from raw suppliers

Silver Hexafluorophosphate >98.0%(T) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-27-36/37/39-45-36/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: F[P-](F)(F)(F)(F)F.[Ag+]
• Uses: Gold Catalysts — 21st Century ′Gold Rush′ It is commonly used as an oxidant forming silver metal. It is often used as a reagent in inorganic and organometallic chemistry. It is used in the preparation of engineering novel materials as well as in preparation of supra molecular Ag(I) complexes. It is used in the development of new catalysts, replacing halide ligands with the weakly coordinating hexafluorophosphate anion.

Technology Process of Silver hexafluorophosphate

There total 8 articles about Silver hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

potassium hexafluorophosphate (17084-13-8) + silver nitrate → silver(I) hexafluorophosphate (26042-63-7)

Guidance literature:

In acetonitrile; at 20 ℃; for 1h; Inert atmosphere; Schlenk technique;

DOI:10.1016/j.poly.2015.02.005

Reference yield:

tert-butylammonium hexafluorophosphate(V) (3109-63-5) + silver nitrate → silver(I) hexafluorophosphate (26042-63-7)

Guidance literature:

In water; acetone; at 20 ℃;

Reference yield:

phosphorus pentafluoride (7647-19-0,874483-74-6) + silver fluoride (11113-87-4) → silver(I) hexafluorophosphate (26042-63-7)

Guidance literature:

In liquid sulphur dioxide; solvent evaporated at ambient temp. in vacuum;;

upstream raw materials:

bromine

silver

silver fluoride

phosphorus pentafluoride

Downstream raw materials:

cymantrene

{C₅H₅(CO)2Mn}2SC₆H₄NO₂⁽¹⁺⁾*PF₆^(1-)*0.5CH₂Cl₂ = {C₅H₅(CO)2Mn}2SC₆H₄NO₂PF₆*0.5CH₂Cl₂

{C₅H₄CH₃(CO)2Mn}2SC₆H₄OCH₃⁽¹⁺⁾*PF₆^(1-) = {C₅H₄CH₃(CO)2Mn}2SC₆H₄OCH₃PF₆

{C₅H₄CH₃(CO)2Mn}2SC₆H₂(CH₃)3⁽¹⁺⁾*PF₆^(1-) = {C₅H₄CH₃(CO)2Mn}2SC₆H₂(CH₃)3PF₆

Refernces

• 1、 Hoge, Berthold,Ke?ler, Mira,Neumann, Beate,R?schenthaler, Gerd-Volker,Stammler, Hans-Georg. "Difluorobis(pentafluoroethyl)phosphoranide: A Promising Building Block for Phosphoranidometal Complexes". supporting information. p. 16466 - 16473. Retrieved 2021/11/13.