Trivinylboroxin

Base Information

• Chemical Name: Trivinylboroxin
• CAS No.: 92988-08-4
• Molecular Formula: C6H9B3O3
• Molecular Weight: 161.569
• Hs Code.: 2934999090
• European Community (EC) Number: 675-971-2
• Nikkaji Number: J1.788.920F
• Mol file: 92988-08-4.mol

Synonyms:trivinylboroxin;92988-08-4;2,4,6-trivinyl-1,3,5,2,4,6-trioxatriborinane;2,4,6-tris(ethenyl)-1,3,5,2,4,6-trioxatriborinane;2,4,6-trivinylcyclotriboroxane;TRIETHENYL-1,3,5,2,4,6-TRIOXATRIBORINANE;triethenylboroxin;Boroxin, triethenyl-;trivinyl cyclotriboroxane;2,4,6-Trivinylboroxin;SCHEMBL359692;2,4,6-trivinyl-cyclotriboroxane;WBRSYBLNSTYNPP-UHFFFAOYSA-N;AKOS006230693;FT-0687231;EN300-104165

Chemical Property of Trivinylboroxin

Chemical Property:

• Vapor Pressure: 24.3mmHg at 25°C
• Refractive Index: 1.389
• Boiling Point: 113.755 °C at 760 mmHg
• Flash Point: 22.599 °C
• PSA: 27.69000
• Density: 0.896 g/cm³
• LogP: 0.69000
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 3
• Exact Mass: 162.0830846
• Heavy Atom Count: 12
• Complexity: 151

Purity/Quality:

98%min ^*data from raw suppliers

BOROXIN, 2,4,6-TRIETHENYL- 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: B1(OB(OB(O1)C=C)C=C)C=C

Technology Process of Trivinylboroxin

There total 3 articles about Trivinylboroxin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Trimethyl borate (121-43-7,63156-11-6) + vinyl magnesium bromide (1826-67-1) → trivinylboroxin (92988-08-4)

Guidance literature:

In tetrahydrofuran; at -78 ℃; for 2h;

DOI:10.1039/b706315f

Reference yield:

Trimethyl borate (121-43-7,63156-11-6) + vinylmagnesium chloride (3536-96-7) → trivinylboroxin (92988-08-4)

Guidance literature:

In not given;

DOI:10.1021/ja01501a029 DOI:10.1021/jo01057a524

Reference yield:

vinylboronic acid dibutyl ester (6336-45-4) → trivinylboroxin (92988-08-4)

Guidance literature:

With 10H-phenothiazine; In water;

DOI:10.1021/jo01057a524

upstream raw materials:

vinylboronic acid dibutyl ester

Trimethyl borate

vinyl magnesium bromide

vinylmagnesium chloride

Downstream raw materials:

(2-vinylphenyl)carbamic acid tert-butyl ester

(4-fluoro-2-vinylphenyl)carbamic acid tert-butyl ester

(4-methoxy-2-vinylphenyl)carbamic acid tert-butyl ester

2-vinylaniline

Refernces

• 1、 Bower, John F.,Williams, Andrew J.,Woodward, Hannah L.,Szeto, Peter,Lawrence, Ron M.,Gallagher, Timothy. "Reactivity of cyclic sulfamidates towards phosphonate-stabilised enolates: Synthesis and applications of α-phosphono lactams". . p. 2636 - 2644. Retrieved 2008/03/11.