rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride

Base Information

• Chemical Name: rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride
• CAS No.: 100163-29-9
• Molecular Formula: C20H24Cl2Zr
• Molecular Weight: 426.53
• Mol file: 100163-29-9.mol

Synonyms:Zirconium,dichloro[1,2-ethanediylbis[(1,2,3,3a,7a-h)-4,5,6,7-tetrahydro-1H-inden-1-ylidene]]-,stereoisomer;1H-Indene, 1,1'-(1,2-ethanediyl)bis[4,5,6,7-tetrahydro-,zirconium complex;Rac-(ethylenebis(h5-4,5,6,7-tetrahydro-1-indenyl))dichlorozirconium;Rac-Ethylenebis(tetrahydroindenyl)zirconium dichloride;Rac-[ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride;Rac-[ethylenebis(4,5,6,7-tetrahydroindenyl)]zirconium dichloride;Racemicethylene-1,2-bis(4,5,6,7-tetrahydro-1-indenyl)zirconium dichloride;rac-Dichloro[1,2-ethylene-1,1'-bis(h5-4,5,6,7-tetrahydro-1-indenylidene)]zirconium;rac-Ethylenebis(4,5,6,7-tetrahydroindenyl)zirconium dichloride;

Chemical Property of rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride

Chemical Property:

• Melting Point: 267-271 °C(lit.)
• PSA: 0.00000
• LogP: 6.58500
• Sensitive.: moisture sensitive

Purity/Quality:

98%,99%, ^*data from raw suppliers

Rac-Ethylenebis(tetrahydroindenyl)zirconiumDichloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C,Xi
• Hazard Codes: C,Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39-45-36

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Rac-Ethylenebis(tetrahydroindenyl)zirconium Dichloride is a catalyst for enantioselective methylalumination of monosubstituted alkenes.The Kaminsky catalyst with co-catalyst methylaluminoxane (MAO) is a type of Ziegler-Natta catalyst, showing extremely high activity for polymerization of olefins such as ethylene, propylene, and styrene. Catalyst for:Regiochemistry in Negishi carboaluminationsPolymerization of olefinsDiastereoselective intramolecular olefin alkylationsAsymmetric carbomagnesiationReduction of esters to alcoholsEnantioselective synthesis of allylic amines