benzotriazolylmethyl phenylmethyl thioether

Base Information

• Chemical Name: benzotriazolylmethyl phenylmethyl thioether
• CAS No.: 111198-04-0
• Molecular Formula: C₁₄H₁₃N₃S
• Molecular Weight: 255.343
• Mol file: 111198-04-0.mol

Synonyms:benzotriazolylmethyl phenylmethyl thioether

Chemical Property of benzotriazolylmethyl phenylmethyl thioether

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of benzotriazolylmethyl phenylmethyl thioether

There total 8 articles about benzotriazolylmethyl phenylmethyl thioether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

benzyl bromide (100-39-0) + Benzotriazol-1-yl-methanethiol (5745-53-9) → benzotriazolylmethyl phenylmethyl thioether (111198-04-0)

Guidance literature:

With triethylamine; In dichloromethane; for 12h; Ambient temperature;

DOI:10.1002/jhet.5570330661

Reference yield: 84.0%

dibenzyl disulphide (150-60-7) + 1-(chloromethyl)-1H-benzotriazole (54187-96-1) → benzotriazolylmethyl phenylmethyl thioether (111198-04-0)

Guidance literature:

dibenzyl disulphide; With N,N,N,N,N,N-hexamethylphosphoric triamide; samarium diiodide; In tetrahydrofuran; at 40 ℃; for 1h;

1-(chloromethyl)-1H-benzotriazole; In tetrahydrofuran; at 20 ℃; for 14h;

DOI:10.1080/00397919808004912

Reference yield: 72.0%

1-(chloromethyl)-1H-benzotriazole (54187-96-1) + benzyl thiosulphate (6313-36-6) → benzotriazolylmethyl phenylmethyl thioether (111198-04-0)

Guidance literature:

benzyl thiosulphate; With samarium diiodide; In tetrahydrofuran; at 70 ℃;

1-(chloromethyl)-1H-benzotriazole; In tetrahydrofuran; at 20 ℃; for 16h;

DOI:10.1080/00397919808004912

upstream raw materials:

1-(chloromethyl)-1H-benzotriazole

2-thiocresol

benzyl bromide

Benzotriazol-1-yl-methanethiol

Refernces

• 1、 Katritzky, Alan R.,Ghiviriga, Ion,Oniciu, Daniela C.,Soti, Ferenc. "1-(Mercaptomethyl)benzotriazole: Preparation, Reactivity and Synthetic Utility". . p. 1927 - 1934. Retrieved 2007/10/03.