2-Hydroxy-2-phenyl-1,1,1-tris-(phenylmercapto)-aethan

Base Information

• Chemical Name: 2-Hydroxy-2-phenyl-1,1,1-tris-(phenylmercapto)-aethan
• CAS No.: 14758-41-9
• Molecular Formula: C₂₆H₂₂OS₃
• Molecular Weight: 446.658
• Mol file: 14758-41-9.mol

Synonyms:2-Hydroxy-2-phenyl-1,1,1-tris-(phenylmercapto)-aethan

Chemical Property of 2-Hydroxy-2-phenyl-1,1,1-tris-(phenylmercapto)-aethan

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-Hydroxy-2-phenyl-1,1,1-tris-(phenylmercapto)-aethan

There total 3 articles about 2-Hydroxy-2-phenyl-1,1,1-tris-(phenylmercapto)-aethan which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

tris(phenylthio)methane (4832-52-4) + benzaldehyde (100-52-7) → 2-Hydroxy-2-phenyl-1,1,1-tris-(phenylmercapto)-aethan (14758-41-9)

Guidance literature:

With n-butyllithium; In tetrahydrofuran;

DOI:10.1016/S0040-4039(01)82051-7

Reference yield:

benzaldehyde (100-52-7) + C28H36O3S3Ti → 2-Hydroxy-2-phenyl-1,1,1-tris-(phenylmercapto)-aethan (14758-41-9)

Guidance literature:

In tetrahydrofuran; for 16h; Yield given; -70 deg C to room temperature;

DOI:10.1002/hlca.19810640136

Reference yield:

→ 2-Hydroxy-2-phenyl-1,1,1-tris-(phenylmercapto)-aethan (14758-41-9)

Guidance literature:

Tris-phenylmercapto-methan, 1) Butyl-Lithium, Pentan, (+)-(S,S)-1,4-Dimethylamino-2,3-dimethoxy-butan, -78grad, 2) Benzaldehyd; <--> bevorzugte Bldg. v. (R)-14>;

DOI:10.1002/hlca.19790620603

upstream raw materials:

tris(phenylthio)methane

benzaldehyde

Downstream raw materials:

(RS)-methyl mandelate

1,1,2-Tris(phenylmercapto)-2-phenyl-aethen

(2-phenylethene-1,1-diyl)bis(phenylsulfane)

benzyl 2-hydroxy-2-phenylacetate

Refernces

• 1、 Denis,Desauvage,Hevesi,Krief. "New synthetic routes to vinyl sulfides, ketene thioacetals and their seleno analogues from carbonyl compounds". . p. 4009 - 4012. Retrieved 2007/10/02.