(E)-1-(2,4,5-triphenylimidazolyl)-1,2-dibenzoylethylene

Base Information

• Chemical Name: (E)-1-(2,4,5-triphenylimidazolyl)-1,2-dibenzoylethylene
• CAS No.: 103456-86-6
• Molecular Formula: C₃₇H₂₆N₂O₂
• Molecular Weight: 530.626
• Mol file: 103456-86-6.mol

Synonyms:(E)-1-(2,4,5-triphenylimidazolyl)-1,2-dibenzoylethylene

Chemical Property of (E)-1-(2,4,5-triphenylimidazolyl)-1,2-dibenzoylethylene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (E)-1-(2,4,5-triphenylimidazolyl)-1,2-dibenzoylethylene

There total 1 articles about (E)-1-(2,4,5-triphenylimidazolyl)-1,2-dibenzoylethylene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

lophine (484-47-9) + 1,4-diphenyl-but-2-yne-1,4-dione (1087-09-8) → (Z)-1-(2,4,5-triphenylimidazolyl)-1,2-dibenzoylethylene (103456-87-7) + (E)-1-(2,4,5-triphenylimidazolyl)-1,2-dibenzoylethylene (103456-86-6)

Guidance literature:

In acetonitrile; for 10h; Heating;

DOI:10.1021/jo00368a003

Reference yield: 25.0%

methanol (67-56-1) + (E)-1-(2,4,5-triphenylimidazolyl)-1,2-dibenzoylethylene (103456-86-6) → lophine (484-47-9) + trans-1-methoxy-1,2-dibenzoylethylene (878544-79-7) + (E)-1,4-Diphenyl-2-(2-phenyl-phenanthro[9,10-d]imidazol-1-yl)-but-2-ene-1,4-dione (103477-28-7) + (E)-1,4-Diphenyl-2-((7aR,7bR)-2-phenyl-7a,7b-dihydro-phenanthro[9,10-d]imidazol-1-yl)-but-2-ene-1,4-dione (103456-96-8)

Guidance literature:

for 1.5h; Further byproducts given; Irradiation;

DOI:10.1021/jo00368a003

Reference yield: 22.0%

(E)-1-(2,4,5-triphenylimidazolyl)-1,2-dibenzoylethylene (103456-86-6) → (E)-1,4-Diphenyl-2-(2-phenyl-phenanthro[9,10-d]imidazol-1-yl)-but-2-ene-1,4-dione (103477-28-7) + threo-5,6-dibenzoyl-5,6-dihydro-2,3-diphenylimidazolo<2,1-a>isoquinoline (103456-97-9) + (E)-1,4-Diphenyl-2-((7aR,7bR)-2-phenyl-7a,7b-dihydro-phenanthro[9,10-d]imidazol-1-yl)-but-2-ene-1,4-dione (103456-96-8) + 1,4-diphenylbut-2-ene-1,4-dione (959-28-4)

Guidance literature:

In benzene; for 1.5h; Further byproducts given; Irradiation;

DOI:10.1021/jo00368a003

upstream raw materials:

lophine

1,4-diphenyl-but-2-yne-1,4-dione

Downstream raw materials:

lophine

trans-1-methoxy-1,2-dibenzoylethylene

(E)-1,4-Diphenyl-2-(2-phenyl-phenanthro[9,10-d]imidazol-1-yl)-but-2-ene-1,4-dione

(E)-1,4-Diphenyl-2-((7aR,7bR)-2-phenyl-7a,7b-dihydro-phenanthro[9,10-d]imidazol-1-yl)-but-2-ene-1,4-dione

Refernces