Technology Process of bis[μ-[n,n'-bis(1-methylethyl)-ethanimidamidato-κn:κn']]di-copper
There total 4 articles about bis[μ-[n,n'-bis(1-methylethyl)-ethanimidamidato-κn:κn']]di-copper which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
methyllithium;
In
diethyl ether;
under N2 atm. soln. MeLi in Et2O was added at -30°C to soln. amidine in Et2O, stirred for 2 h at room temp. and added to CuCl in Et2O, stirred for 18 h; solvent was removed in vacuo, residue was extd. with hexane, filtered, concd. in vacuo, and cooled to -30°C; elem. anal.;
DOI:10.1021/ic048492u
- Guidance literature:
-
In
diethyl ether;
under N2 atm. soln. MeLi in Et2O was added dropwise to soln. 1,3-diisopropylcabodiimide in Et2O at -30°C, react. mixt. was warmed to roomtemp., stirred for 4 h, added to soln. CuBr in Et2O and stirred for 12 h under exclusion of light; volatiles were removed under reduced pressure, residue was extd. with hexane, filtered through Celite, concd. and cooled to -30°C, sublimation; elem. anal.;
DOI:10.1021/ic0345424
- Guidance literature:
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Multi-step reaction with 2 steps
1: Schlenk technique; Inert atmosphere
2: Schlenk technique; Inert atmosphere
DOI:10.1002/open.201600105
