1,3,3-trimethylcyclohexenyl chloride

Base Information

• Chemical Name: 1,3,3-trimethylcyclohexenyl chloride
• CAS No.: 101679-28-1
• Molecular Formula: C₉H₁₅Cl
• Molecular Weight: 158.671
• Mol file: 101679-28-1.mol

Synonyms:1,3,3-trimethylcyclohexenyl chloride

Chemical Property of 1,3,3-trimethylcyclohexenyl chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,3,3-trimethylcyclohexenyl chloride

There total 4 articles about 1,3,3-trimethylcyclohexenyl chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

1,1-dichloro-2,2,6-trimethylcyclohexane (1453111-17-5) → 1,3,3-trimethylcyclohexenyl chloride (101679-28-1)

Guidance literature:

With morpholine; In dimethyl sulfoxide; benzene; at 100 ℃; for 24h;

DOI:10.2298/JSC120501015A

Reference yield:

1-chloro-2,6-dimethyl-hepta-1,5-diene (17081-70-8) → 1,3,3-trimethylcyclohexenyl chloride (101679-28-1)

Guidance literature:

With sulfuric acid; In acetic acid;

DOI:10.1002/jlac.19677040106

Reference yield:

6-Methyl-hept-5-en-2-on (110-93-0,129085-68-3) → 1,3,3-trimethylcyclohexenyl chloride (101679-28-1)

Guidance literature:

Multi-step reaction with 2 steps

1: (i) PhLi, piperidine, (ii) /BRN= 1741705/

2: H₂SO₄ / acetic acid

With sulfuric acid; In acetic acid;

DOI:10.1002/jlac.19677040106

upstream raw materials:

1-chloro-2,6-dimethyl-hepta-1,5-diene

6-Methyl-hept-5-en-2-on

2,2,6-trimethyl-cyclohexanone hydrazone

1,1-dichloro-2,2,6-trimethylcyclohexane

Downstream raw materials:

(4-Isopropyl-2,3-dimethoxy-6-methyl-phenyl)-(2,6,6-trimethyl-cyclohex-1-enyl)-methanone

2-(3-isopropyl-4,5-dimethoxyphenyl)-1-(2,6,6-trimethylcyclohex-1-en-1-yl)ethanone

2,6,6-trimethyl-cyclohex-1-enecarboxylic acid

1-(1,3,3-trimethylcyclohexenyl)-4-isopropyl-5,6-dimethoxybenzocyclobutenol

Refernces

• 1、 K?brich,Breckoff,Drischel. "A new synthetic principle for compounds in the vitamin A series". . p. 51 - 69. Retrieved 2007/10/06.