[(N2)(bis(dicyclohexyl)-1,4-phosphinobutane)Ru(μ-Cl)3RuCl(bis(dicyclohexyl)-1,4-phosphinobutane)]

Base Information

• Chemical Name: [(N2)(bis(dicyclohexyl)-1,4-phosphinobutane)Ru(μ-Cl)3RuCl(bis(dicyclohexyl)-1,4-phosphinobutane)]
• CAS No.: 371233-99-7
• Molecular Formula: C₅₆H₁₀₄Cl₄N₂P₄Ru₂
• Molecular Weight: 1273.3
• Mol file: 371233-99-7.mol

Synonyms:[(N2)(bis(dicyclohexyl)-1,4-phosphinobutane)Ru(μ-Cl)3RuCl(bis(dicyclohexyl)-1,4-phosphinobutane)]

Chemical Property of [(N2)(bis(dicyclohexyl)-1,4-phosphinobutane)Ru(μ-Cl)3RuCl(bis(dicyclohexyl)-1,4-phosphinobutane)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(N2)(bis(dicyclohexyl)-1,4-phosphinobutane)Ru(μ-Cl)3RuCl(bis(dicyclohexyl)-1,4-phosphinobutane)]

There total 1 articles about [(N2)(bis(dicyclohexyl)-1,4-phosphinobutane)Ru(μ-Cl)3RuCl(bis(dicyclohexyl)-1,4-phosphinobutane)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) + 1,4-bis(dicyclohexylphosphino)butane (65038-36-0) + nitrogen (7727-37-9) → [(N2)(bis(dicyclohexyl)-1,4-phosphinobutane)Ru(μ-Cl)3RuCl(bis(dicyclohexyl)-1,4-phosphinobutane)] (371233-99-7)

Guidance literature:

In benzene; byproducts: PPh3; soln. of Ru complex stirred at 21°C under N2 for 18 h; suspn. diluted with hexane; product filtered off, washed with hexane anddried under a steady flow of N2 for 24 h; elem. anal.;

DOI:10.1139/v00-208

Reference yield: 95.0%

[(N2)(bis(dicyclohexyl)-1,4-phosphinobutane)Ru(μ-Cl)3RuCl(bis(dicyclohexyl)-1,4-phosphinobutane)] (371233-99-7) + di-μ-chlorobis[(2,3,4,5-η)-3,4-dinaphthalen-2-yl-2,5-diphenylcyclopenta-2,4-dien-1-one]dirhodium - chloroform (1/0.2) + acetone (67-64-1) → [butane-1,4-diylbis[dicyclohexylphosphine-κP]]tri-μ-chloro([(2,3,4,5-η)-3,4-dinaphthalen-2-yl-2,5-diphenylcyclopenta-2,4-dien-1-one]rhodium)(propan-2-one)ruthenium - water (1/0.5)

Guidance literature:

In dichloromethane; acetone; under inert atm., Schlenk techniques; soln. of ((dcypb)(N2)Ru(μ-Cl)3RuCl(dcypb)) and (RhCl(η4-Ph2(Nph)2C4CO))2 in CH2Cl2/acetone (9/1); soln. evapd., residue washed with pentane and dried in vacuo; elem. anal.;

DOI:10.1002/hlca.200590028

Reference yield: 88.0%

[(N2)(bis(dicyclohexyl)-1,4-phosphinobutane)Ru(μ-Cl)3RuCl(bis(dicyclohexyl)-1,4-phosphinobutane)] (371233-99-7) + 1,1-diphenyl-2-propyn-1-ol (3923-52-2) → RuCl(1,4-bis(dicyclohexylphosphino)butane)(μ-Cl)3Ru(1,4-bis(dicyclohexylphosphino)butane)(C=CHC(OH)Ph2)

Guidance literature:

In benzene; (N2); stirring a soln. of alkyne and ruthenium complex in benzene at 22°C for 12 h; addn. of hexanes, filtration, washing with hexanes, drying in vac.; elem. anal.;

DOI:10.1021/om0110888

upstream raw materials:

tris(triphenylphosphine)ruthenium(II) chloride

1,4-bis(dicyclohexylphosphino)butane

nitrogen

Downstream raw materials:

trans,cis,cis-RuCl₂(bis(dicyclohexyl)-1,4-phosphinobutane)(CO)2

2-chloro-1,3-di-tert-butyl-1,3-diaza-2-silacyclopent-4-ene

Refernces