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(1R)-(-)-Camphorquinone

Base Information Edit
  • Chemical Name:(1R)-(-)-Camphorquinone
  • CAS No.:10334-26-6
  • Deprecated CAS:465-29-2
  • Molecular Formula:C10H14O2
  • Molecular Weight:166.22
  • Hs Code.:2914299000
  • European Community (EC) Number:626-988-9
  • UNII:RAL3591W33
  • Nikkaji Number:J232.216A
  • Wikidata:Q27116959
  • Metabolomics Workbench ID:28182
  • Mol file:10334-26-6.mol
(1R)-(-)-Camphorquinone

Synonyms:camphorquinone

Suppliers and Price of (1R)-(-)-Camphorquinone
Supply Marketing:Edit
Business phase:
The product has achieved commercial mass production*data from LookChem market partment
Manufacturers and distributors:
  • Manufacture/Brand
  • Chemicals and raw materials
  • Packaging
  • price
  • TRC
  • (1R)-(-)Camphorquinone
  • 1g
  • $ 140.00
  • TCI Chemical
  • (1R)-(-)-Camphorquinone >98.0%(GC)
  • 1g
  • $ 33.00
  • TCI Chemical
  • (1R)-(-)-Camphorquinone >98.0%(GC)
  • 5g
  • $ 96.00
  • Sigma-Aldrich
  • (1R)-(?)-Camphorquinone 99%
  • 5g
  • $ 111.00
  • Sigma-Aldrich
  • (1R)-(?)-Camphorquinone analytical standard
  • 50mg
  • $ 49.30
  • Crysdot
  • (1R,4S)-1,7,7-Trimethylbicyclo[2.2.1]heptane-2,3-dione 95+%
  • 100g
  • $ 633.00
  • Chem-Impex
  • (1R)-(-)-Camphorquinon,98%(GC) 98%(GC)
  • 1G
  • $ 31.36
  • Chem-Impex
  • (1R)-(-)-Camphorquinon,98%(GC) 98%(GC)
  • 5G
  • $ 100.80
  • Biosynth Carbosynth
  • (1R)-(-)-Camphorquinone
  • 2 g
  • $ 90.00
  • Biosynth Carbosynth
  • (1R)-(-)-Camphorquinone
  • 1 g
  • $ 50.00
Total 34 raw suppliers
Chemical Property of (1R)-(-)-Camphorquinone Edit
Chemical Property:
  • Vapor Pressure:0.0817mmHg at 25°C 
  • Melting Point:200-203 °C(lit.) 
  • Refractive Index:1.5 
  • Boiling Point:226.473 °C at 760 mmHg 
  • Flash Point:82.965 °C 
  • PSA:34.14000 
  • Density:1.098 g/cm3 
  • LogP:1.58070 
  • Storage Temp.:Store below +30°C. 
  • Solubility.:almost transparency in Methanol 
  • XLogP3:1.5
  • Hydrogen Bond Donor Count:0
  • Hydrogen Bond Acceptor Count:2
  • Rotatable Bond Count:0
  • Exact Mass:166.099379685
  • Heavy Atom Count:12
  • Complexity:278
Purity/Quality:

98%,99%, *data from raw suppliers

(1R)-(-)Camphorquinone *data from reagent suppliers

Safty Information:
  • Pictogram(s): HarmfulXn 
  • Hazard Codes:Xn 
  • Statements: 22-43 
  • Safety Statements: 36/37 
MSDS Files:

SDS file from LookChem

Useful:
  • Canonical SMILES:CC1(C2CCC1(C(=O)C2=O)C)C
  • Isomeric SMILES:C[C@@]12CC[C@@H](C1(C)C)C(=O)C2=O
  • Uses (1R)-(-)Camphorquinone are used as visible light photoinitiator for biomedical applications such as in dental surgery. (1R)-(?)-Camphorquinone can be used as a chiral starting material for the preparation of: α-Hydroxycamphors by selective reduction of keto groups using various vegetables. Camphor-1,2-diamine platinum(II) complexes for DNA interaction studies. Camphoric anhydride by unsensitized photo-oxidation in the presence of oxygen and polar solvents. Camphorquinone-based chiral homoallylic amine, which is reacted with aldehydes to produce homoallylic primary amines via imine formation followed by 2-azonia-Cope rearrangement. (1R)-(-)-Camphorquinone may be used as an analytical standard for the determination of the analyte in dental resin composite restorations in the oral environment in contact with food and beverages, and biological samples by analytical techniques.
Technology Process of (1R)-(-)-Camphorquinone

There total 122 articles about (1R)-(-)-Camphorquinone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
With hydrogenchloride; formaldehyd; Heating;
DOI:10.1080/00397919908086451
Guidance literature:
With selenium(IV) oxide; In ethanol; at 150 ℃; for 1.25h; microwave irradiation;
DOI:10.1080/00397910500501557
Guidance literature:
With bromine; dimethyl sulfoxide; In chloroform; at 20 ℃; for 0.75h;
DOI:10.1016/S0040-4039(03)01045-1
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