Ethylene-13C2

Base Information

• Chemical Name: Ethylene-13C2
• CAS No.: 51915-19-6
• Molecular Formula: C2H4
• Molecular Weight: 30.0318
• European Community (EC) Number: 685-189-3
• DSSTox Substance ID: DTXSID90482058
• Nikkaji Number: J847.518K
• Wikidata: Q82317948
• Mol file: 51915-19-6.mol

Synonyms:Ethylene-13C2;51915-19-6;(1,2-13C2)ethene;Ethylene(1,2-13c2);DTXSID90482058;Ethylene-13C2, 99 atom % 13C

Chemical Property of Ethylene-13C2

Chemical Property:

• Melting Point: 130-145 °C(lit.)
• Boiling Point: −104 °C(lit.)
• PSA: 0.00000
• LogP: 0.80220
• XLogP3: 1.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 30.038009798
• Heavy Atom Count: 2
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

Ethylene-13C2 99 atom % ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F+
• Hazard Codes: F+
• Statements: 12-67
• Safety Statements: 9-16-33-46-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=C
• Isomeric SMILES: [13CH2]=[13CH2]

Technology Process of Ethylene-13C2

There total 10 articles about Ethylene-13C2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[13C]Carbon monoxide (1641-69-6) → methane (6532-48-5) + methane (34557-54-5,27936-85-2) + ethane (74-84-0) + ethene (74-85-1) + ethane-13C2 (52026-74-1) + [13C2]ethene (51915-19-6)

Guidance literature:

With sodium dithionite; Phosphocreatine; carbide containing iron-molybdenum co-factor of molybdenum nitrogenase; His-tagged Fe protein; ATP; magnesium chloride; creatine phosphokinase; In aq. buffer; at 30 ℃; for 3h; pH=8;

DOI:10.1021/ja401698d

Reference yield:

ethanol-1-13C (14742-23-5) → carbon monoxide-13C-18O (35907-63-2) + carbon dioxide-13C-18O1 (20201-82-5) + methane (6532-48-5) + ethane-13C1 (6145-17-1) + methane (34557-54-5,27936-85-2) + ethane (74-84-0) + ethene (74-85-1) + ethane-13C2 (52026-74-1) + [13C2]ethene (51915-19-6) + mono-[13C]-ethylene (6145-18-2) + carbon dioxide (124-38-9,18923-20-1) + carbon monoxide (55125-78-5) + carbon dioxide (1111-72-4) + [13C]Carbon monoxide (1641-69-6) + carbon dioxide (2537-69-1) + CO(18)O (18983-82-9) + carbon dioxide (2684-00-6)

Guidance literature:

With ¹⁸O-labeled water; at 350 ℃; Reagent/catalyst; Inert atmosphere;

DOI:10.1002/anie.201604388

Reference yield:

ethanol-1-13C (14742-23-5) → carbon monoxide-13C-18O (35907-63-2) + carbon dioxide-13C-18O1 (20201-82-5) + methane (6532-48-5) + ethane-13C1 (6145-17-1) + methane (34557-54-5,27936-85-2) + ethane (74-84-0) + ethene (74-85-1) + ethane-13C2 (52026-74-1) + [13C2]ethene (51915-19-6) + mono-[13C]-ethylene (6145-18-2) + carbon monoxide (55125-78-5) + carbon dioxide (1111-72-4) + [13C]Carbon monoxide (1641-69-6) + carbon dioxide (2537-69-1) + CO(18)O (18983-82-9) + carbon dioxide (2684-00-6)

Guidance literature:

With ¹⁸O-labeled water; at 350 ℃; Inert atmosphere;

DOI:10.1002/anie.201604388

upstream raw materials:

RhCl(⁽¹³⁾C₂H₄){CH₃C(CH₂P(C₆H₅)2)3}

sodium tetraethylborate

[13C]Carbon monoxide

[¹³C]methanol

Downstream raw materials:

Pd(P(C(CH₃)3)2CH₂C₆H₄)N(C₆H₅)2(⁽¹³⁾CH₂⁽¹³⁾CH₂)

C₁₀⁽¹³⁾CH₁₄

styrene-α, β-¹³C₂

[(2,6-bis(4-tBuC₆H₃)₂pyridine dianion)Au(eta²-¹³C₂H₄)][CF₃COOB(C₆F₅)₄]

Refernces

• 1、 Ilias, Samia,Bhan, Aditya. "The mechanism of aromatic dealkylation in methanol-to-hydrocarbons conversion on H-ZSM-5: What are the aromatic precursors to light olefins?". . p. 6 - 16. Retrieved 2014/01/06.
• 2、 Westg?rd Erichsen, Marius,Svelle, Stian,Olsbye, Unni. "The influence of catalyst acid strength on the methanol to hydrocarbons (MTH) reaction". . p. 216 - 223. Retrieved 2013/09/02.