Sodium formate-13C

Base Information

• Chemical Name: Sodium formate-13C
• CAS No.: 23102-86-5
• Molecular Formula: ¹³CHNaO2
• Molecular Weight: 68.9965
• European Community (EC) Number: 693-173-2
• Nikkaji Number: J1.919.154K
• Mol file: 23102-86-5.mol

Synonyms:Sodium formate-13C;23102-86-5;Sodium Formate-1-13C;sodium;oxo(113C)methanolate;Formate-13C (sodium);Formic-13C acid sodium salt;Sodiumformate-13C;HY-W088065S;MFCD00064569;AKOS015913260;Sodium formate-13C, 99 atom % 13C;CS-0514486;J-014988

Chemical Property of Sodium formate-13C

Chemical Property:

• Melting Point: 259-262 °C(lit.)
• PSA: 40.13000
• LogP: -0.99800
• Storage Temp.: Refrigerator
• Solubility.: Water
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 68.99077839
• Heavy Atom Count: 4
• Complexity: 13.5

Purity/Quality:

99% ^*data from raw suppliers

Sodium Formate-1-13C ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=O)[O-].[Na+]
• Isomeric SMILES: [13CH](=O)[O-].[Na+]
• Uses: SODIUM FORMATE-13C is used in various organic reactions and syntheses. It is used in the preparation of [3,2b]pyridines as well as the palladium-catalyzed coupling of vinyl triflates with organos tannanes. Labelled Sodium Formate is used in various organic reactions and syntheses. It is used in the preparation of [3,2b]pyridines as well as the palladium-catalyzed coupling of vinyl triflates with organostannanes.

Technology Process of Sodium formate-13C

There total 5 articles about Sodium formate-13C which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

(13C)-formic acid (1633-56-3) → sodium (13)C-formate (23102-86-5)

Guidance literature:

With sodium hydroxide; In water; at 20 ℃; for 0.166667h;

DOI:10.1039/c8dt03056a

Reference yield:

sodium hydrogen carbonate-13C (87081-58-1) + sodium carbonate (497-19-8) → sodium (13)C-formate (23102-86-5) + sodium formate (141-53-7)

Guidance literature:

With nickel; hydrogen; In water; at 200 ℃; for 2h; under 45004.5 Torr; Overall yield = 84.1 %; Green chemistry;

DOI:10.1039/c6gc02866g

Reference yield:

sodium hydrogen carbonate-13C (87081-58-1) → sodium (13)C-formate (23102-86-5) + Na(1+)*(2)H(13)COO(1-)=Na(2)H(13)COO

Guidance literature:

With hydrogen; In water-d2; Pd catalyst suspended in soln. of NaH(13)CO3 in D2O, H2 purged slowly; not isolated, detected by NMR;

DOI:10.1021/ja00358a026

upstream raw materials:

sodium hydrogen carbonate-¹³C

carbon dioxide

(¹³C)-formic acid

sodium carbonate

Downstream raw materials:

<1-¹³C>-Ameisensaeure-ethylester

[13C]Carbon monoxide

sodium hydroxide

-p-toluic acid

Refernces

• 1、 Schindler, Tobias,Paparo, Albert,Nishiyama, Haruka,Spaniol, Thomas P.,Tsurugi, Hayato,Mashima, Kazushi,Okuda, Jun. "Deprotonation of a formato ligand by a: Cis-coordinated carbyne ligand within a bis(phenolate) tungsten complex". supporting information. p. 13328 - 13331. Retrieved 2018/10/17.
• 2、 Kim, Dong-Su,Park, Woo-Jin,Lee, Chang-Hee,Jun, Chul-Ho. "Hydroesterification of alkenes with sodium formate and alcohols promoted by cooperative catalysis of Ru3(CO)12 and 2-pyridinemethanol". . p. 12191 - 12196. Retrieved 2015/01/09.