Neodymium(III) chloride hexahydrate

Base Information

• Chemical Name: Neodymium(III) chloride hexahydrate
• CAS No.: 13477-89-9
• Molecular Formula: (x)Cl₃Nd*(x)H₂O
• Molecular Weight: 358.69
• Hs Code.: 28469024
• European Community (EC) Number: 629-622-6
• DSSTox Substance ID: DTXSID50593053
• Mol file: 13477-89-9.mol

Synonyms:Neodymium(III) chloride hexahydrate;13477-89-9;neodymium(3+);trichloride;hexahydrate;H12Cl3NdO6;DTXSID50593053;Neodymium chloride--water (1/3/6);neodymium(3+) hexahydrate trichloride;AKOS030228775;DB-266234

Chemical Property of Neodymium(III) chloride hexahydrate

Chemical Property:

• Appearance/Colour: purple crystals, crystalline powder or chunks
• Melting Point: 124 °C(lit.)
• PSA: 55.38000
• Density: 2.282 g/cm³
• LogP: 1.68270
• Storage Temp.: 0-6°C
• Water Solubility.: 2.46 parts per 1 part H2O [MER06]; soluble alcohol [HAW93]
• Hydrogen Bond Donor Count: 6
• Hydrogen Bond Acceptor Count: 9
• Rotatable Bond Count: 0
• Exact Mass: 354.87768
• Heavy Atom Count: 10
• Complexity: 0

Purity/Quality:

98%,99%, ^*data from raw suppliers

Neodymium(III) chloride hydrate (99.997%-Nd) (REO) PURATREM ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: O.O.O.O.O.O.[Cl-].[Cl-].[Cl-].[Nd+3]
• Uses: Neodymium(III) chloride hexahydrate may be used as a source of Nd3+ ions, to be used to dope AgBr crystals, known to exhibit lasing effects.

Technology Process of Neodymium(III) chloride hexahydrate

There total 13 articles about Neodymium(III) chloride hexahydrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + neodymium(III) oxide → neodymium(III) chloride hexahydrate (13477-89-9)

Guidance literature:

In hydrogenchloride; oxide dissoln., water boiling off (stirring), pptn. until thick slurry obtained, slurry cooling to room temp.; solid filtration off, vac. treating at 40°C (grinding, stirring);

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + neodymium(III) oxide + water (7732-18-5) → neodymium(III) chloride hexahydrate (13477-89-9)

Guidance literature:

In hydrogenchloride; Nd2O3 dissolved in aq. HCl; evapd. at 100°C until crystal film formed;

DOI:10.1002/zaac.200900495

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + neodymium(III) oxide → neodymium(III) chloride hydrate (13477-89-9)

Guidance literature:

In hydrogenchloride; Nd2O3 dissolved in aq. HCl (1:1); soln. evapd.; ppt. recrystd. from methanol;

DOI:10.1016/j.jallcom.2004.03.079

upstream raw materials:

hydrogenchloride

water

methanol

Downstream raw materials:

neodymium trichloride monohydrate

((HSC₆H₄NHCOCH₂NCH₂COOC₂H₄)2NCH₂COO)Nd

Refernces

• 1、 Wan, Yong-Hong,Jin, Lin-Pei,Wang, Ke-Zhi. "Hydrothermal synthesis and structural characterization of two novel lanthanide supramolecular coordination polymers with nano-chains". . p. 85 - 93. Retrieved 2003.
• 2、 Wang, Feng,Fan, Xianping,Pi, Daibo,Wang, Zhiyu,Wang, Minquan. "Hydrothermal synthesis and luminescence behavior of rare-earth-doped NaLa(WO4)2 powders". . p. 825 - 830. Retrieved 2005.
• 3、 Meshkova,Topilova,Devyatykh,Gusev,Shul'Gin. "IR luminescence of neodymium(III) and ytterbium(III) ions in complexes with N-alkyl-substituted 2-aminobenzoic acids". . p. 262 - 266. Retrieved 2011/05/06.
• 4、 Sun, Lining,Dang, Song,Yu, Jiangbo,Feng, Jing,Shi, Liyi,Zhang, Hongjie. "Near-infrared luminescence from visible-light-sensitized hybrid materials covalently linked with tris(8-hydroxyquinolinate)-lanthanide [Er(III), Nd(III), and Yb(III)] derivatives". . p. 16393 - 16397. Retrieved 2011/05/14.